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Merck
CN

714747

Biphenyl-3,4′,5-tricarboxylic acid

greener alternative

96%

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About This Item

Empirical Formula (Hill Notation):
C15H10O6
CAS Number:
Molecular Weight:
286.24
UNSPSC Code:
26111700
PubChem Substance ID:
MDL number:
Assay:
96%
Form:
powder
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InChI

1S/C15H10O6/c16-13(17)9-3-1-8(2-4-9)10-5-11(14(18)19)7-12(6-10)15(20)21/h1-7H,(H,16,17)(H,18,19)(H,20,21)

SMILES string

OC(=O)c1ccc(cc1)-c2cc(cc(c2)C(O)=O)C(O)=O

InChI key

LQEZHWGJSWHXPJ-UHFFFAOYSA-N

assay

96%

form

powder

greener alternative product characteristics

Design for Energy Efficiency
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sustainability

Greener Alternative Product

mp

>300 °C

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General description

Biphenyl-3,4′,5-tricarboxylic acid (H3BPT) is a co-ordination polymer, which is majorly used as an unsymmetrically substituted linker. It forms self-assembly under the solvothermal condition to synthesize 3D lanthanide based metal organic frameworks (MOFs).
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Application

Biphenyl-3,4′,5-tricarboxylic acid (H3BPT) may be used to prepare porous metal-organic frameworks (MOFs) for gas adsorption, photocatalytic activity and magnetic properties. H3BPT and (bis)imidazole linkers may be used to prepare coordination polymers (CPs) by hydrothermal process. CPs may be used in gas storage, catalysis, ion exchange etc.

pictograms

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Hazard Classifications

Aquatic Acute 1 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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Two (3, 6)-connected porous metal?organic frameworks based on linear trinuclear [Co 3 (COO) 6] and paddlewheel dinuclear [Cu 2 (COO) 4] SBUs: gas adsorption, photocatalytic behaviour, and magnetic properties.
Zhao J, et al.
Journal of Material Chemistry A, 3(13), 6962-6969 (2015)
Crystal structures, fluorescent and magnetic properties of five new coordination polymers based on biphenyl-3, 4?, 5-tricarboxylic acid
Lu Y, et al.
Journal of Solid State Chemistry, 192, 144-152 (2012)
Synthesis, structure and luminescent property of a new europium-based coordination polymer constructed from biphenyl-3, 4?, 5-tricarboxylic acid.
Yan D and Duan Q
Inorganic Chemistry Communications, 36, 188-191 (2013)

Articles

Metal-organic frameworks offer high surface area materials for alternative energy applications through simple synthetic strategies.

金属有机骨架是配位聚合物的一部分,代表了大量替代能源应用的一个强大的新工具。通过提供定制的高表面积材料的简单的合成策略可以很容易获得MOF。

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