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Merck
CN

715425

Chloro[1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene]copper(I)

95%, powder

Sustainability features

Synonym(s):

[1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene]copper(I) chloride

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About This Item

Empirical Formula (Hill Notation):
C21H24ClCuN2
CAS Number:
Molecular Weight:
403.43
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
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Product Name

Chloro[1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene]copper(I), 95%

Quality Segment

assay

95%

form

powder

reaction suitability

core: copper, reagent type: catalyst

sustainability

Sustainability features

mp

273-277 °C

greener alternative category

storage temp.

2-8°C

SMILES string

Cc1cc(C)c(N2C=CN(\C2=[Cu]/Cl)c3c(C)cc(C)cc3C)c(C)c1

InChI

1S/C21H24N2.ClH.Cu/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;;/h7-12H,1-6H3;1H;/q;;+1/p-1

InChI key

JMQRNHTTZWNLMH-UHFFFAOYSA-M

General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This product falls under category 12 PAP and aligns with the Green Chemistry Principle of Catalysis. Click here for more information.

Application

Catalyst for:
  • Hydroboration of terminal alkynes
  • Click reaction of azides with terminal alkynes
  • Hydrosilylation of ketones and azide-alkyne cycloadditions
  • Regioselective boron addition to internal alkynes
  • Hydroboration
  • Methylenation-Diels-alder cyclization


Storage Class

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable



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