Skip to Content
Merck
CN

717398

(S)[(Sp)-2-(Diphenylphosphino)ferrocenyl]-4-isopropyloxazoline

97%

Synonym(s):

(Sp)-1-(Diphenylphosphino)-2-[(4S)-4-isopropyl-2-oxazolyl]ferrocene

Sign In to View Organizational & Contract Pricing.

Select a Size

About This Item

Empirical Formula (Hill Notation):
C28H28FeNOP
CAS Number:
163169-29-7
Molecular Weight:
481.35
NACRES:
NA.22
PubChem Substance ID:
329763485
UNSPSC Code:
12352005
MDL number:
MFCD15144869

Key Documents

View All Documentation
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

InChI

1S/C23H23NOP.C5H5.Fe/c1-17(2)21-16-25-23(24-21)20-14-9-15-22(20)26(18-10-5-3-6-11-18)19-12-7-4-8-13-19;1-2-4-5-3-1;/h3-15,17,21H,16H2,1-2H3;1-5H;/t21-;;/m1../s1

SMILES string

[Fe].[CH]1[CH][CH][CH][CH]1.CC(C)[C@H]2COC(=N2)[C]3[CH][CH][CH][C]3P(c4ccccc4)c5ccccc5

InChI key

FELCHLOAEMNOQM-GHVWMZMZSA-N

assay

97%

form

solid

optical activity

[α]20/D 366°, c = 0.1 in chloroform

mp

158-162 °C

functional group

ether, phosphine

Quality Level

100

Related Categories

Application

(S)[(Sp)-2-(Diphenylphosphino)ferrocenyl]-4-isopropyloxazoline can be used as a chiral ligand in the synthesis of rhodium, iridium, ruthenium, and osmium metal complexes.

Legal Information

Sold under license from Kanata Chemical Technologies Inc. for research purposes only.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
MKCL8817
MKCM0843
MKCL1721
MKBC5380

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Synthesis and structure of chiral-at-metal complexes with the ligand (S)-2-[(Sp)-2-(diphenylphosphino) ferrocenyl]-4-isopropyloxazoline
Carmona D, et al.
Journal of Organometallic Chemistry, 691(26), 5560-5566 (2006)
Octahedral ruthenium (II) complexes containing the chiral ligand (4S)-2-[(Sp)-2-(diphenylphosphino) ferrocenyl]-4-(isopropyl) oxazoline (FcPN). X-Ray crystal structures of fac-[RuCl2 (PMe3) 2 (FcPN)] and fac-[RuCl2 (dppm)(FcPN)](dppm= bis (diphenylphosphino)methane)
Gimeno J, et al.
Journal of Organometallic Chemistry, 637, 463-468 (2001)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service