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Merck
CN

718114

Manganese(II) chloride bis(lithium chloride) complex solution

0.5 M in THF, liquid, density: 95%6 g/mL at 25 °C

Synonym(s):

Lithium tetrachloromanganate(II) solution, Lithium chloromanganate(II), Lithium manganese chloride, Manganese(II) chloride bis(lithium chloride) complex solution

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About This Item

Linear Formula:
Li2MnCl4
CAS Number:
Molecular Weight:
210.63
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
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Product Name

Manganese(II) chloride bis(lithium chloride) complex solution, density: 0.956 g/mL at 25 °C, 0.5 M in THF

form

liquid

Quality Segment

reaction suitability

core: manganese, reagent type: inorganic catalyst

concentration

0.5 M in THF

density

0.956 g/mL at 25 °C

SMILES string

[Li+].[Li+].Cl[Mn--](Cl)(Cl)Cl

InChI

1S/4ClH.2Li.Mn/h4*1H;;;/q;;;;2*+1;+2/p-4

InChI key

VJOUQNFWQPCDPE-UHFFFAOYSA-J

Application

Catalyst for homocoupling of Grignard reagents using atmospheric oxygen as an oxidant

Reactant for:
  • Transmetalation reactions
  • Nickel-imidazolium carbene-catalyzed coupling reactions

Reagent for the preparation of Rieke manganese


Signal Word

Danger

supp_hazards

Storage Class

3 - Flammable liquids

Flash Point (°F)

1.4 °F - closed cup

Flash Point (°C)

-17.0 °C - closed cup

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Central nervous system, Respiratory system



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