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Merck
CN

718114

Manganese(II) chloride bis(lithium chloride) complex solution

0.5 M in THF, liquid, density: 95%6 g/mL at 25 °C

Synonym(s):

Lithium tetrachloromanganate(II) solution, Lithium chloromanganate(II), Lithium manganese chloride, Manganese(II) chloride bis(lithium chloride) complex solution

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About This Item

Linear Formula:
Li2MnCl4
CAS Number:
Molecular Weight:
210.63
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
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Product Name

Manganese(II) chloride bis(lithium chloride) complex solution, 0.5 M in THF, density: 0.956 g/mL at 25 °C

SMILES string

[Li+].[Li+].Cl[Mn--](Cl)(Cl)Cl

InChI key

VJOUQNFWQPCDPE-UHFFFAOYSA-J

InChI

1S/4ClH.2Li.Mn/h4*1H;;;/q;;;;2*+1;+2/p-4

form

liquid

reaction suitability

core: manganese, reagent type: catalyst

concentration

0.5 M in THF

density

0.956 g/mL at 25 °C

Quality Level

Application

Catalyst for homocoupling of Grignard reagents using atmospheric oxygen as an oxidant

Reactant for:
  • Transmetalation reactions
  • Nickel-imidazolium carbene-catalyzed coupling reactions

Reagent for the preparation of Rieke manganese

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

supp_hazards

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

1.4 °F - closed cup

flash_point_c

-17.0 °C - closed cup

Regulatory Information

危险化学品
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José M Concellón et al.
The Journal of organic chemistry, 72(21), 7974-7979 (2007-09-25)
A complete E-selective synthesis of alpha,beta-unsaturated amides through a sequential reaction of a range of dichloroamides with a variety of aldehydes promoted by Rieke manganese (Mn*) is reported. A mechanism based on a sequential aldol-type reaction and a completely stereoselective
A. Leleu, et al.,
Advanced Synthesis & Catalysis, 348, 1086-1092 (2006)
A. Eloi, et al.,
Organometallics, 28, 925-928 (2009)
Manganese- or iron-catalyzed homocoupling of grignard reagents using atmospheric oxygen as an oxidant.
Gérard Cahiez et al.
Journal of the American Chemical Society, 129(45), 13788-13789 (2007-10-20)

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