718386
Lithium diisobutyl-tert-butoxyaluminum hydride solution
0.25 M in THF/hexanes
Synonym(s):
LDBBA
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About This Item
Empirical Formula (Hill Notation):
C12H28AlLiO
CAS Number:
Molecular Weight:
222.27
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
form
liquid
Quality Segment
reaction suitability
reagent type: reductant
concentration
0.25 M in THF/hexanes
density
0.795 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
[Li+].CC(C)C[AlH-](CC(C)C)OC(C)(C)C
InChI
1S/C4H9O.2C4H9.Al.Li.H/c1-4(2,3)5;2*1-4(2)3;;;/h1-3H3;2*4H,1H2,2-3H3;;;/q-1;;;;+1;
InChI key
HNIYOHKCLUHKGY-UHFFFAOYSA-N
Application
Lithiumdiisobutyl-tert-butoxyaluminum hydride solution can be used as a reducing agent for the reduction of:
- Aromatic and aliphatic nitriles to aldehydes.
- Aromatic and aliphatic esters to aldehydes.
- Tertiary amides to aldehydes.
Signal Word
Danger
Precautionary Statements
Target Organs
Central nervous system, Respiratory system
supp_hazards
Storage Class
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 3
Hazard Classifications
Aquatic Chronic 2 - Asp. Tox. 1 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT SE 3 - Water-react. 2
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