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Merck
CN

720526

Palladium(π-cinnamyl) chloride dimer

97%, solid

Synonym(s):

Bis[cinnamyl palladium(II) chloride], Palladium(1-phenylallyl)chloride dimer, [(Cinnamyl)PdCl]2, [Pd(1-phenylallyl)Cl]2

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About This Item

Empirical Formula (Hill Notation):
C18H18Cl2Pd2
CAS Number:
Molecular Weight:
518.08
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
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Product Name

Palladium(π-cinnamyl) chloride dimer, 97%

Quality Segment

assay

97%

form

solid

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

mp

218-220 °C

storage temp.

2-8°C

SMILES string

Cl[Pd].Cl[Pd].[CH2][CH][CH]c1ccccc1.[CH2][CH][CH]c2ccccc2

InChI

1S/2C9H9.2ClH.2Pd/c2*1-2-6-9-7-4-3-5-8-9;;;;/h2*2-8H,1H2;2*1H;;/q;;;;2*+1/p-2

InChI key

SHWAPUDBEQXXLQ-UHFFFAOYSA-L

Application

Palladium(π-cinnamyl) chloride dimer can be used as a catalyst for the:
  • Ammonia cross-coupling reactions to synthesize arylamines.
  • Conversion of aryl triflates to fluorides.

It can also be used as a source of palladium in the asymmetric α-arylation of amides.


Storage Class

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable



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