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Merck
CN

723002

Cyanomethyl methyl(phenyl)carbamodithioate

98% (HPLC)

Synonym(s):

Cyanomethyl N-methyl-N-phenyl dithiocarbamate

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About This Item

Empirical Formula (Hill Notation):
C10H10N2S2
CAS Number:
Molecular Weight:
222.33
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
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Product Name

Cyanomethyl methyl(phenyl)carbamodithioate, 98% (HPLC)

InChI

1S/C10H10N2S2/c1-12(10(13)14-8-7-11)9-5-3-2-4-6-9/h2-6H,8H2,1H3

SMILES string

CN(C(=S)SCC#N)c1ccccc1

InChI key

FYACMHCOSCVNHO-UHFFFAOYSA-N

assay

98% (HPLC)

form

powder

mol wt

average Mn 8,000

mp

88-92 °C

storage temp.

2-8°C

Quality Level

Application

RAFT agent for controlled radical polymerization; especially suited for the polymerization of vinyl ester and vinyl amide monomers. Chain Transfer Agent (CTA)

General description

Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Skin Sens. 1

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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RAFT Agent Design and Synthesis
Keddie, D. J.; et al.
Macromolecules, 45, 5321-5342 (2012)
Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being

Articles

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

RAFT polymerization offers living characteristics to radical polymerization, contributing versatility to reversible deactivation radical polymerization methods.

Over the past two decades, the rapid advance of controlled living polymerization (CLP) techniques.

Micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization.

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Protocols

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

RAFT polymerization offers precise control, enabling tailored synthesis of complex polymer structures.

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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