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726192

Bis(4-methylphenyl)iodonium hexafluorophosphate

98%

Synonym(s):

Bis(p-tolyl)iodonium hexafluorophosphate

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About This Item

Empirical Formula (Hill Notation):
C14H14F6IP
CAS Number:
60565-88-0
Molecular Weight:
454.13
UNSPSC Code:
12352300
NACRES:
NA.23
PubChem Substance ID:
329764214
EC Number:
262-301-5
Beilstein/REAXYS Number:
3581445
MDL number:
MFCD06656584
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Quality Segment

100

assay

≥97.5% (TLC), 98%

form

solid

SMILES string

F[P-](F)(F)(F)(F)F.Cc1ccc([I+]c2ccc(C)cc2)cc1

InChI

1S/C14H14I.F6P/c1-11-3-7-13(8-4-11)15-14-9-5-12(2)6-10-14;1-7(2,3,4,5)6/h3-10H,1-2H3;/q+1;-1

InChI key

LHLVGWWCRPPKBC-UHFFFAOYSA-N

General description

Bis(4-methylphenyl)iodonium hexafluorophosphate is a white powder. It melts at 175-180 °C and shows an UV absorption peak at 267nm. 1

Application


  • Covalent Functionalisation of Few-Layer Black Phosphorus using Aryl Iodonium Salts and Comparison to Diazonium Modified Black Phosphorus: Explores the functionalization of black phosphorus using bis(4-methylphenyl)iodonium hexafluorophosphate and compares it to diazonium modification (M Van Druenen, 2019).

  • Iodonium sulfonates as high‐performance coinitiators and additives for CQ‐based systems: Toward aromatic amine‐free photoinitiating systems: Examines the effectiveness of iodonium sulfonates and bis(4-methylphenyl)iodonium hexafluorophosphate in CQ-based photoinitiating systems (J Kirschner et al., 2019).

  • Thiophene-substituted phenothiazine-based photosensitisers for radical and cationic photopolymerization reactions under visible laser beams (405 and 455 nm): Studies the use of thiophene-substituted phenothiazine in combination with bis(4-methylphenyl)iodonium hexafluorophosphate for effective photopolymerization (P Chao et al., 2016).

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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