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About This Item
Empirical Formula (Hill Notation):
CeO2
Molecular Weight:
172.11
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
26111700
MDL number:
InChI key
AQGZISMLQKBRRO-UHFFFAOYSA-N
SMILES string
[Sm].O=[Ce]=O
InChI
1S/Ce.2O.Sm
form
pellets (for sputtering)
contains
15 mol % samarium as dopant
composition
Sm0.15Ce0.85O2
greener alternative product characteristics
Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
diam. × L
2-3 mm × 3-5 mm
greener alternative category
General description
Cerium(IV) oxide-samarium doped pellets (15% mol samarium doped) (SDC-15) is an electrolytic material with a high oxygen ion conductivity. Samarium ion acts as an aliovalent cation that can be incorporated into the host lattice to increase the oxygen vacancy concentration and improve the oxide ion conduction in cerium oxide. It can be synthesized by reverse strike co-precipitation technique.
Samarium doped ceria may be used as an electrolyte in solid oxide fuel cells (SOFCs). Electrical conductivity as a function of temperature of doped ceria was investigated in a study. Relation of dopant type, oxygen vacancy ordering and ionic conductivity was investigated by transmission electron microscopy and electron energy loss spectroscopy.
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Application
Cerium(IV) oxide-samarium doped can be used in the fabrication of solid oxide fuel cells (SOFCs), which can further be used as sustainable sources of alternative energy.
Storage Class
11 - Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
监管及禁止进口产品
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Hossein Negahban et al.
Clinical rheumatology, 34(1), 35-42 (2014-02-11)
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Effect of Gd (Sm) doping on properties of ceria electrolyte for solid oxide fuel cells,
Zha S, et al.
Journal of Power Sources, 115(1), 44-48 (2003)
Samarium-doped ceria nanowires: novel synthesis and application in low-temperature solid oxide fuel Cells
Ma Y, et al.
Advanced Materials, 22(14), 1640-1644 (2010)
Yoshitsugu Mitani et al.
Clinical cancer research : an official journal of the American Association for Cancer Research, 20(24), 6570-6581 (2014-10-16)
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Intermediate-temperature electrochemical performance of a polycrystalline PrBaCo2O5+ δ cathode on samarium-doped ceria electrolyte.
Chen D, et al.
Journal of Power Sources, 188(1), 96-105 (2009)
Articles
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