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About This Item
Empirical Formula (Hill Notation):
C64H74FeN2O4P2
CAS Number:
Molecular Weight:
1053.08
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
Quality Level
assay
≥97%
form
powder
optical purity
ee: ≥99%
functional group
amine, phenyl, phosphine
SMILES string
[Fe].COc1c(C)cc(cc1C)P([C]2[CH][CH][CH][C]2[C@H](N(C)C)c3ccccc3)c4cc(C)c(OC)c(C)c4.COc5c(C)cc(cc5C)P([C]6[CH][CH][CH][C]6[C@H](N(C)C)c7ccccc7)c8cc(C)c(OC)c(C)c8
InChI
1S/2C32H37NO2P.Fe/c2*1-21-17-26(18-22(2)31(21)34-7)36(27-19-23(3)32(35-8)24(4)20-27)29-16-12-15-28(29)30(33(5)6)25-13-10-9-11-14-25;/h2*9-20,30H,1-8H3;/t2*30-;/m11./s1
InChI key
HEJIDMKBSDYNOY-LJXMUBMNSA-N
General description
Mandyphos SL-M004-1 is a chiral ferrocenyl based diphosphine ligand belonging to the Mandyphos family.
Application
It may be used as a chiral ligand in the rhodium complex-catalyzed hydrogenation reaction, a key step during the synthesis of argatroban.
Packaging
Bottomless glass bottle. Contents are inside inserted fused cone.
Other Notes
sold in collaboration with Solvias AG
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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Find documentation for the products that you have recently purchased in the Document Library.
Modular chiral ligands: the profiling of the Mandyphos and Taniaphos ligand families.
Spindler F, et al.
Tetrahedron Asymmetry, 15(14), 2299-2306 (2004)
Diastereoselective synthesis of an argatroban intermediate, ethyl (2R, 4R)-4-methylpipecolate, by means of a Mandyphos/rhodium complex-catalyzed hydrogenation.
Ferraboschi P, et al.
Tetrahedron Asymmetry, 22(16), 1626-1631 (2011)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 73469-100G | 04061832625836 |
| 73469-100MG | 04061832625843 |
| 73469-1G | 04061826084052 |
| 73469-250G | 04061832625850 |
| 73469-50G | 04061832625874 |
| 73469-5G | 04061832625881 |
| 73469-500MG | 04061832625867 |