735809
[2-（二叔丁基膦基甲基）-6-（二乙基氨基甲基）吡啶]羰基氯氢化钌（II）
powder
别名:
Milstein Catalyst Precursor, [2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]ruthenium(II) chlorocarbonyl hydride
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关于此项目
经验公式（希尔记法）:
C20H36ClN2OPRu
化学文摘社编号:
分子量:
488.01
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
[2-（二叔丁基膦基甲基）-6-（二乙基氨基甲基）吡啶]羰基氯氢化钌（II）,
form
powder
reaction suitability
core: ruthenium, reagent type: catalyst
greener alternative product characteristics
Catalysis
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sustainability
Greener Alternative Product
greener alternative category
SMILES string
Cl[RuH].[C-]#[O+].CCN(CC)Cc1cccc(CP(C(C)(C)C)C(C)(C)C)n1
InChI
1S/C19H35N2P.CO.ClH.Ru.H/c1-9-21(10-2)14-16-12-11-13-17(20-16)15-22(18(3,4)5)19(6,7)8;1-2;;;/h11-13H,9-10,14-15H2,1-8H3;;1H;;/q;;;+1;/p-1
InChI key
RZCAJPSOQUIHSH-UHFFFAOYSA-M
General description
May contain up to 10% acetone and/or THF.
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Application
Precursor to active Ru catalyst for the dehydrogenative coupling of amines and alcohols to form amide bonds.
Precursor to active ruthenium catalyst for greener amide bond formation by dehydrogenative coupling of amines and alcohols.
Direct Synthesis of Amides from Alcohols and Amines with Liberation of H2
Direct Synthesis of Amides from Alcohols and Amines with Liberation of H2
signalword
Warning
hcodes
Hazard Classifications
Carc. 2 - Eye Irrit. 2
supp_hazards
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable