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735809

[2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]carbonylchlorohydridoruthenium(II)

powder

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Synonym(s):

Milstein Catalyst Precursor, [2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]ruthenium(II) chlorocarbonyl hydride

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About This Item

Empirical Formula (Hill Notation):
C20H36ClN2OPRu
CAS Number:
863971-62-4
Molecular Weight:
488.01
UNSPSC Code:
12352300
PubChem Substance ID:
329765059
NACRES:
NA.22
MDL number:
MFCD16038117
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Product Name

[2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]carbonylchlorohydridoruthenium(II),

form

powder

reaction suitability

core: ruthenium, reagent type: catalyst

greener alternative product characteristics

Catalysis
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Greener Alternative Product

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Aligned,

SMILES string

Cl[RuH].[C-]#[O+].CCN(CC)Cc1cccc(CP(C(C)(C)C)C(C)(C)C)n1

InChI

1S/C19H35N2P.CO.ClH.Ru.H/c1-9-21(10-2)14-16-12-11-13-17(20-16)15-22(18(3,4)5)19(6,7)8;1-2;;;/h11-13H,9-10,14-15H2,1-8H3;;1H;;/q;;;+1;/p-1

InChI key

RZCAJPSOQUIHSH-UHFFFAOYSA-M

General description

May contain up to 10% acetone and/or THF.
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Application

Precursor to active Ru catalyst for the dehydrogenative coupling of amines and alcohols to form amide bonds.
Precursor to active ruthenium catalyst for greener amide bond formation by dehydrogenative coupling of amines and alcohols.

Direct Synthesis of Amides from Alcohols and Amines with Liberation of H2

pictograms

Health hazardExclamation mark
GHS08,GHS07

signalword

Warning

hcodes

H319,H351

Hazard Classifications

Carc. 2 - Eye Irrit. 2

supp_hazards

EUH019

Storage Class

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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