739103
Ru-MACHO®
solid
Synonym(s):
Carbonylchlorohydrido{bis[2-(diphenylphosphinomethyl)ethyl]amino}ethyl]amino}ruthenium(II), {Bis[2-(diphenylphosphino)ethyl]amine}carboynlchlorohydridoruthenium(II)
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About This Item
Product Name
Ru-MACHO®,
form
solid
Quality Segment
reaction suitability
core: ruthenium, reagent type: catalyst
mp
260-290 °C
SMILES string
Cl[Ru].[C-]#[O+].C(CP(c1ccccc1)c2ccccc2)NCCP(c3ccccc3)c4ccccc4
InChI
1S/C28H29NP2.CO.ClH.Ru/c1-5-13-25(14-6-1)30(26-15-7-2-8-16-26)23-21-29-22-24-31(27-17-9-3-10-18-27)28-19-11-4-12-20-28;1-2;;/h1-20,29H,21-24H2;;1H;/q;;;+1/p-1
InChI key
GQFWSAKCCNATEV-UHFFFAOYSA-M
Application
<li><strong>Dehydrogenative Intramolecular Macrolactonization:</strong> Ru-MACHO catalyst is applied in dehydrogenative intramolecular macrolactonization of dihydroxy compounds, demonstrating its efficiency in organic synthesis with potential implications for pharmaceutical synthesis (Jamdade et al., 2022).</li>
<li><strong>Acceptorless Dehydrogenation of Methanol:</strong> Employing Ru-MACHO catalyst in the acceptorless dehydrogenation of methanol to produce carbon monoxide and hydrogen, this process highlights Ru-MACHO′s capability in catalytic transformations and green chemistry applications (Kaithal et al., 2021).</li>
<li><strong>Precapture and Hydrogenation of CO2:</strong> A study on the heterogenized Ru-MACHO catalytic systems for pre-capture and hydrogenation of CO2 into methanol, underscoring the catalyst′s potential in sustainable chemical processes (Szego et al., 2023).</li>
<li><strong>Pressure-dependent Hydrogenative Depolymerization:</strong> The Ru-MACHO catalyst is used for highly selective pressure-dependent hydrogenative depolymerization of polybutylene succinate, demonstrating the catalyst′s versatility in polymer processing and chemical recycling (Johnson et al., 2024).</li>
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Legal Information
Signal Word
Warning
Hazard Codes
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
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