740608
tert-Butyl (tert-butyldimethylsilyl)glyoxylate
97%
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About This Item
Assay
97%
form
liquid
refractive index
n20/D 1.440
density
0.920 g/mL at 25 °C
functional group
ester
SMILES string
CC(C)(C)OC(=O)C(=O)[Si](C)(C)C(C)(C)C
InChI
1S/C12H24O3Si/c1-11(2,3)15-9(13)10(14)16(7,8)12(4,5)6/h1-8H3
InChI key
GGYHTNUVBJRLDM-UHFFFAOYSA-N
Application
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
190.9 °F
Flash Point(C)
88.3 °C
Regulatory Information
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The Johnson group has developed a family of reagents that are useful for the modular preparation of highly substituted glycolic acid derivatives. Silyl glyoxylates are potent electrophiles by virtue of being α-dicarbonyls, and react with a variety of nucleophiles.
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