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741108

Pentafluorophenyl methacrylate

Name: Pentafluorophenyl methacrylate
Brand: ALDRICH

contains MEHQ as inhibitor, 95%

Synonym(s):

Methacrylic acid, pentafluorophenyl ester

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About This Item

Empirical Formula (Hill Notation):

C₁₀H₅F₅O₂

CAS Number:

13642-97-2

Molecular Weight:

252.14

NACRES:

NA.23

PubChem Substance ID:

329765465

UNSPSC Code:

12162002

MDL number:

MFCD00042332

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Properties

Quality Level

100

assay

95%

form

liquid

contains

MEHQ as inhibitor

refractive index

n20/D 1.438

density

1.394 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

CC(=C)C(=O)Oc1c(F)c(F)c(F)c(F)c1F

InChI

1S/C10H5F5O2/c1-3(2)10(16)17-9-7(14)5(12)4(11)6(13)8(9)15/h1H2,2H3

InChI key

NIJWSVFNELSKMF-UHFFFAOYSA-N

Description

Application

The PFP unit acts as an activated ester for coupling (esterification/amidation) reactions. This is also a monomer for low refractive index polymers (n ~1.40).

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

172.0 °F

flash_point_c

77.8 °C

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Surface reactivity of pulsed-plasma polymerized pentafluorophenyl methacrylate (PFM) toward amines and proteins in solution.

L Francesch et al.

Langmuir : the ACS journal of surfaces and colloids, 23(7), 3927-3931 (2007-03-07)

Pulsed-plasma polymerization has been used to deposit ultrathin layers of pentafluorophenyl methacrylate by using low duty cycles and low power input. The monomer structure can be retained such that the chemical reactivity of the active ester group could be studied

[Copolymerization of methyl methacrylate with pentafluorophenyl methacrylate and physical characteristics of the polymers (author's transl)].

Y Kadoma et al.

Iyo Kizai Kenkyujo hokoku. Reports of the Institute for Medical and Dental Engineering, Tokyo Medical and Dental University, 15, 23-29 (1981-01-01)

Side-chain peptide-synthetic polymer conjugates via tandem "ester-amide/thiol-ene" post-polymerization modification of poly(pentafluorophenyl methacrylate) obtained using ATRP.

Nikhil K Singha et al.

Biomacromolecules, 12(8), 2908-2913 (2011-07-08)

Herein the concept of tandem postpolymerization modification as a versatile route to synthesize well-defined, highly functionalized polymers is introduced. Poly(pentafluorophenyl methacrylate) obtained by atom transfer radical polymerization was first modified with allylamine, which displaces the active ester to give well-defined

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Global Trade Item Number

SKU	GTIN
741108-1G	04061826175767
741108-5G	04061832929385