746177
MIBA
96%
Synonym(s):
5-Methoxy-2-iodophenylboronic acid
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About This Item
Empirical Formula (Hill Notation):
C7H8BIO3
CAS Number:
Molecular Weight:
277.85
NACRES:
NA.06
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
Assay:
96%
Form:
solid
Quality Level
assay
96%
form
solid
greener alternative product characteristics
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
mp
202-207 °C
functional group
iodo
greener alternative category
, Aligned
storage temp.
2-8°C
SMILES string
OB(O)C1=C(I)C=CC(OC)=C1
InChI
1S/C7H8BIO3/c1-12-5-2-3-7(9)6(4-5)8(10)11/h2-4,10-11H,1H3
InChI key
XQYAEIDOJUNIGY-UHFFFAOYSA-N
General description
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalysis. Find details here.
Application
MIBA can be used to promote direct amidations of carboxylic acids and amines in catalytic amounts. This technology avoids the requirement of preactivation of the carboxylic acid or use of coupling reagents.
Used to promote greener amidations of carboxylic acids and amines in catalytic amounts. This technology avoids the requirement of preactivation of the carboxylic acid or use of coupling reagents.
Direct Amidation of Carboxylic Acids Catalyzed by ortho-Iodo Arylboronic Acids: Catalyst Optimization, Scope, and Preliminary Mechanistic Study Supporting a Peculiar Halogen Acceleration Effect
Direct Amidation of Carboxylic Acids Catalyzed by ortho-Iodo Arylboronic Acids: Catalyst Optimization, Scope, and Preliminary Mechanistic Study Supporting a Peculiar Halogen Acceleration Effect
Legal Information
This Product is licensed from GreenCentre Canada for non-commercial, research use only. Please contact GreenCentre Canada for information regarding commercial use of Product.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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The importance of amides as a component of biomolecules and synthetic products motivates the development of catalytic, direct amidation methods employing free carboxylic acids and amines that circumvent the need for stoichiometric activation or coupling reagents. ortho-Iodophenylboronic acid 4a has
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 746177-250MG | 04061833229644 |
| 746177-1G | 04061826645345 |