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Merck
CN

747785

[Ru(bpm)3][Cl]2

powder

Synonym(s):

Dichlorotris(2,2′-bipyrimidine-N1,N1′)ruthenium(II), Tris(2,2′-bipyrimide)ruthenium(II) dichloride

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About This Item

Empirical Formula (Hill Notation):
C24H18Cl2N12Ru
CAS Number:
65034-88-0
Molecular Weight:
646.46
UNSPSC Code:
12161600
NACRES:
NA.22

Key Documents

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Product Name

[Ru(bpm)3][Cl]2,

SMILES string

C1(C2=NC=CC=N2)=NC=CC=N1.C3(C4=NC=CC=N4)=NC=CC=N3.C5(C6=NC=CC=N6)=NC=CC=N5.[Cl-].[Cl-].[Ru+2]

InChI

1S/3C8H6N4.2ClH.Ru/c3*1-3-9-7(10-4-1)8-11-5-2-6-12-8;;;/h3*1-6H;2*1H;/q;;;;;+2/p-2

InChI key

DVHNMJRXSLLELA-UHFFFAOYSA-L

form

powder

reaction suitability

core: ruthenium, reagent type: catalyst
reaction type: Photocatalysis

impurities

≤15 wt. % ethylene glycol

mp

>300 °C

Quality Level

100

Related Categories

General description

[Ru(bpm)3][Cl]2 is used as a photoredox catalyst in direct methoxycyclization reactions.

Application

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

pictograms

Health hazard
GHS08

signalword

Warning

hcodes

H373

Hazard Classifications

STOT RE 2 Oral

target_organs

Kidney

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCW4129
MKCQ4105
MKCK5177
MKCJ0117
MKCF4262

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Photoredox-assisted gold-catalyzed arylative alkoxycyclization of 1, 6-enynes
Mayans JG, et al.
Organic Letters, 22(8), 3045-3049 (2020)

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