747807
CyJohnPhos Pd G2
solid
Synonym(s):
Chloro(2-dicyclohexylphosphino-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II), CyJohnPhos-G2, CyJohnPhos-Pd-G2
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About This Item
Product Name
CyJohnPhos Pd G2,
SMILES string
NC1=CC=CC=C1C2=CC=CC=C2[Pd]Cl.P(C3CCCCC3)(C4=C(C5=CC=CC=C5)C=CC=C4)C6CCCCC6
InChI key
PLKOENXOQXWSIL-UHFFFAOYSA-M
InChI
1S/C24H31P.C12H10N.ClH.Pd/c1-4-12-20(13-5-1)23-18-10-11-19-24(23)25(21-14-6-2-7-15-21)22-16-8-3-9-17-22;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;/h1,4-5,10-13,18-19,21-22H,2-3,6-9,14-17H2;1-6,8-9H,13H2;1H;/q;;;+1/p-1
Quality Level
product line
Buchwald precatalyst Generation 2
form
solid
feature
generation 2
reaction suitability
core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplings
mp
178-183 °C (decomposition without melting)
functional group
phosphine
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Buchwald precatalysts and ligands are bulky electron-rich dialkylbiaryl phospine-based catalysts and structurally related ligands that improve reactivity in Pd-catalyzed cross - coupling reactions
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