749613
4-(4,6-Dimethoxy-1,3,5-triazin-2-yl)-4-methylmorpholinium tetrafluoroborate
97%
Synonym(s):
DMTMM, MMTM
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About This Item
Empirical Formula (Hill Notation):
C10H17BF4N4O3
Molecular Weight:
328.07
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
Assay:
97%
Form:
solid
Quality Level
assay
97%
form
solid
mp
202-207 °C
functional group
ether
SMILES string
F[B-](F)(F)F.COc1nc(OC)nc(n1)[N+]2(C)CCOCC2
InChI
1S/C10H17N4O3.BF4/c1-14(4-6-17-7-5-14)8-11-9(15-2)13-10(12-8)16-3;2-1(3,4)5/h4-7H2,1-3H3;/q+1;-1
InChI key
LCRXDNPNQMIQFZ-UHFFFAOYSA-N
Application
4-(4,6-Dimethoxy-1,3,5-triazin-2-yl)-4-methylmorpholinium tetrafluoroborate (DMTMM BF4) can be used as a coupling reagent alternative to DMTMM Cl in peptide synthesis because of its stability. It is also used in the synthesis of:
- Esters and peptides in both solution and solid-phase.
- γ-aminobutyric acid (GABA)-containing cyclic heptapeptide, unguisin A.
- The cyclization of linear tetrapeptides.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Maria Laura Alfieri et al.
Antioxidants (Basel, Switzerland), 9(3) (2020-03-22)
The ability of gelatin-based hydrogels of incorporating and releasing under controlled conditions 5,6-dihydroxyindole-2-carboxylic acid (DHICA), a melanin-related metabolite endowed with marked antioxidant properties was investigated. The methyl ester of DHICA, MeDHICA, was also tested in view of its higher stability
An update on new methods to synthesize cyclotetrapeptides
Rodriguez LML, et al
Organic & Biomolecular Chemistry, 13(25), 6906-6921 (2015)
Diego Serrano et al.
Molecular cell, 80(6), 1025-1038 (2020-12-11)
The structural organization of chromosomes is a crucial feature that defines the functional state of genes and genomes. The extent of structural changes experienced by genomes of eukaryotic cells can be dramatic and spans several orders of magnitude. At the
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 749613-5G | 04061833339671 |
| 749613-1G | 04061826653890 |