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Merck
CN

750190

Dichloro[bis(2-(diphenylphosphino)phenyl)ether]palladium(II)

95%, powder

Sustainability features

Synonym(s):

Pd-117

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About This Item

Empirical Formula (Hill Notation):
C36H28Cl2OP2Pd
CAS Number:
Molecular Weight:
715.88
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.22
MDL number:
Assay:
95%
Form:
powder
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Product Name

Dichloro[bis(2-(diphenylphosphino)phenyl)ether]palladium(II), 95%

Quality Segment

assay

95%

form

powder

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Sustainability features

mp

243-250 °C

greener alternative category

storage temp.

2-8°C

SMILES string

Cl[Pd]Cl.O(c1ccccc1P(c2ccccc2)c3ccccc3)c4ccccc4P(c5ccccc5)c6ccccc6

InChI

1S/C36H28OP2.2ClH.Pd/c1-5-17-29(18-6-1)38(30-19-7-2-8-20-30)35-27-15-13-25-33(35)37-34-26-14-16-28-36(34)39(31-21-9-3-10-22-31)32-23-11-4-12-24-32;;;/h1-28H;2*1H;/q;;;+2/p-2

InChI key

VYOUBMJFTDMKRR-UHFFFAOYSA-L

General description

Dichloro[bis(2-(diphenylphosphino)phenyl)ether]palladium(II) is a palladium(II) complex containing two chloride ligands and two (2-(diphenylphosphino)phenyl)ether ligands coordinated to the palladium center. It is used as a catalyst for the cross-coupling reaction of 2-brom-1,3-dienes to prepare high stereoselectivity of conjugated Z, E dienes.
Sustainability Features: Aligned with Green Chemistry principle, ′Catalysis,′ this product is a DPEPhos-based palladium catalyst for efficient cross-coupling reactions. The wide bite angle diphosphine ligand enables superior performance in challenging Suzuki-Miyaura couplings. Click here for more information.

Application

Dichloro[bis(2-(diphenylphosphino)phenyl)ether]palladium(II) is used as an efficient catalyst in the coupling reaction.


Storage Class

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable



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