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Merck
CN

751626

Poly(ethylene glycol) methyl ether (4-cyano-4-pentanoate dodecyl trithiocarbonate)

average Mn 5,400

Synonym(s):

Dodecyl-trithiocarbonate-cyano PEG, PEG-RAFT, Poly(ethylene glycol)methyl ether 4-cyano-4-[(dodecylsulfanylthiocarbonyl)sulfanyl]pentanoate

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About This Item

NACRES:
NA.23
UNSPSC Code:
12352100
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form

solid

Quality Level

mol wt

average Mn 5,400

transition temp

Tm 55-60 °C

PDI

≤1.1

Ω-end

4-cyano-4-pentanoate dodecyl trithiocarbonate

α-end

methoxy

storage temp.

2-8°C

General description

Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.

Application

RAFT agent for controlled radical polymerization; especially suited for the polymerization of styrene, acrylate, and acrylamide monomers to make lithographically and biologically important PEG-block copolymers. Chain Transfer Agent (CTA)


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Storage Class

11 - Combustible Solids

wgk

WGK 3



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Protocols

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

Articles

Reversible addition–fragmentation chain transfer (RAFT) polymerization is rapidly moving to the forefront in construction of drug and gene delivery vehicles.

Humankind has utilized protein materials throughout its existence, starting with the use of materials such as wool and silk for warmth and protection from the elements and continuing with the use of recombinant DNA techniques to synthesize proteins with unique and useful properties.

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

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RAFT Agent Design and Synthesis
Keddie, D. J.; et al.
Macromolecules, 45, 5321-5342 (2012)



Global Trade Item Number

SKUGTIN
751626-1G04061826280973
751626-5G04061832978475