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752800

[(S,S)-Teth-TsDpen RuCl]

Name: [<I>(S,S</I>)-Teth-TsDpen RuCl]
Brand: ALDRICH

Synonym(s):

stereoisomer of Chloro[N-[(1S,2S)-1,2-diphenyl-2-[(R)-[3-(η6-phenyl)propyl]amino-κN]ethyl]-4-methylbenzenesulfonamidato-κN]ruthenium

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About This Item

Empirical Formula (Hill Notation):

C₃₀H₃₁ClN₂O₂RuS

CAS Number:

851051-43-9

Molecular Weight:

620.17

MDL number:

MFCD16294984

UNSPSC Code:

12352103

PubChem Substance ID:

329766311

NACRES:

NA.22

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Properties

form

solid

Quality Segment

100

optical activity

[α]22/D +339°, c = 0.5% in chloroform

reaction suitability

core: ruthenium, reagent type: catalyst

mp

260-268 °C

storage temp.

2-8°C

SMILES string

Cc1ccc(cc1)S(=O)(=O)N2[C@H]([C@@H]([N@@H](CCCc3ccccc3)[Ru]2Cl)c4ccccc4)c5ccccc5

InChI

1S/C30H31N2O2S.ClH.Ru/c1-24-19-21-28(22-20-24)35(33,34)32-30(27-17-9-4-10-18-27)29(26-15-7-3-8-16-26)31-23-11-14-25-12-5-2-6-13-25;;/h2-10,12-13,15-22,29-31H,11,14,23H2,1H3;1H;/q-1;;+2/p-1/t29-,30-;;/m0../s1

InChI key

MDABGVLQRDDWLY-ARDORAJISA-M

Description

Application

[(S,S)-Teth-TsDpen RuCl] is a catalyst for the asymmetric hydrogenation of ketones. It can be used as a catalyst:

In the reduction of a ketone intermediate for the synthesis of esketamine.
In asymmetric hydrogenation of acetylenic ketones.
For the preparation of (3S,6S)-1,8-diphenylocta-1,7-diyne-3,6-diol starting from 1,8-diphenylocta-1,7-diyne-3,6-dione.

Storage Class

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

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