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Sigma-Aldrich

Ethyl methyl carbonate

greener alternative

99%

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Synonym(s):
Carbonic acid ethyl methyl ester, EMC, Methyl ethyl carbonate
Empirical Formula (Hill Notation):
C4H8O3
CAS Number:
623-53-0
Molecular Weight:
104.10
MDL number:
MFCD00191398
PubChem Substance ID:
329766467
NACRES:
NA.23

Quality Level

100

Assay

99%

form

liquid

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

refractive index

n20/D 1.378

bp

101 °C

mp

-55 °C

density

1.006 g/mL at 25 °C

application(s)

battery manufacturing

greener alternative category

, Enabling

SMILES string

CCOC(=O)OC

InChI

1S/C4H8O3/c1-3-7-4(5)6-2/h3H2,1-2H3

InChI key

JBTWLSYIZRCDFO-UHFFFAOYSA-N

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General description

Ethyl methyl carbonate (EMC) is a low viscosity solvent, generally prepared by the esterification of chloroformate with ethanol. It can also be prepared by transesterification of dimethyl carbonate (DMC) with ethanol.
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Application

EMC is majorly utilized as a co-solvent in the nonaqueous electrolyte. It enhances the energy density and discharge capacity of lithium-ion batteries.

Pictograms

Flame
GHS02

Signal Word

Danger

Hazard Statements

H225

Hazard Classifications

Flam. Liq. 2

Storage Class Code

3 - Flammable liquids

WGK

WGK 1

Flash Point(F)

75.0 °F

Flash Point(C)

23.9 °C

Regulatory Information

危险化学品

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Metal-organic frameworks as an acid catalyst for the synthesis of ethyl methyl carbonate via transesterification
Zhou Y, et al.
J. Mol. Catal. A: Chem., 308(1-2), 68-72 (2009)
Lithium difluoro (oxalato) borate/ethylene carbonate+ propylene carbonate+ ethyl (methyl) carbonate electrolyte for LiMn2O4 cathode
Fu MH, et al.
Journal of Power Sources, 195(3), 862-866 (2010)
Zeolitic imidazolate framework as efficient heterogeneous catalyst for the synthesis of ethyl methyl carbonate
Zhou X, et al.
J. Mol. Catal. A: Chem., 366, 43-47 (2013)
Shamsudeen F Fagbo et al.
Emerging infectious diseases, 21(11), 1981-1988 (2015-10-21)
We investigated an outbreak of Middle East respiratory syndrome (MERS) at King Fahad Medical City (KFMC), Riyadh, Saudi Arabia, during March 29-May 21, 2014. This outbreak involved 45 patients: 8 infected outside KFMC, 13 long-term patients at KFMC, 23 health
Susanne M Köhler et al.
Vaccine, 33(24), 2771-2777 (2015-04-29)
While proving highly effective in controlling Anthrax in farm animals all over the world currently attenuated live anthrax vaccines employed in a veterinary context suffer from drawbacks such as residual virulence, short term protection, variation in quality and, most importantly
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