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Merck
CN

758388

Pyrazino[2,3-f][1,10]phenanthroline

99% (HPLC)

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About This Item

Empirical Formula (Hill Notation):
C14H8N4
CAS Number:
Molecular Weight:
232.24
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
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Quality Segment

assay

99% (HPLC)

form

solid

manufacturer/tradename

ECACC

mp

310-315 °C

SMILES string

c1cnc2c(c1)c3nccnc3c4cccnc24

InChI

1S/C14H8N4/c1-3-9-11(15-5-1)12-10(4-2-6-16-12)14-13(9)17-7-8-18-14/h1-8H

InChI key

IBOSPAWVGHGUAV-UHFFFAOYSA-N

General description

Pyrazino[2,3-f][1,10]phenanthroline is a ligand which is used in the synthesis of copper(I)- phenanthroline complexes which are used in molecular device technology and in solar-energy conversion. It functions as an electron acceptor and the electron density is delocalized on the quinoxaline ring. The absorption and emission properties and the excited state lifetimes of these phenanthroline based copper complexes can be fine-tuned easily.

Application

  • As an electron accepting ligand in metal complexes which are used in solar cells.
  • Used in the synthesis of ruthenium (II) complexes which are used as DNA probes.

Features and Benefits

Imparts improved directionality of electron transfer in excited copper complexes.


Pictograms

Exclamation mark

Signal Word

Warning

Hazard Codes

Hazard Classifications

Acute Tox. 4 Oral

Storage Class

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable



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