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75920

OXONE® tetrabutylammonium salt

technical, ~1.6% active oxygen basis

Synonym(s):

Tetrabutylammonium OXONE®, Tetrabutylammonium hydrogen monopersulfate, Tetrabutylammonium peroxomonosulfate, Tetrabutylammonium persulfate triple salt

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About This Item

CAS Number:
104548-30-3
MDL number:
MFCD20503057
UNSPSC Code:
12352000
PubChem Substance ID:
24886893
NACRES:
NA.22
Beilstein/REAXYS Number:
5199887
Form:
powder
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Quality Segment

grade

technical

form

powder

reaction suitability

core: ammonium, reaction type: phase-transfer, reagent type: oxidant

concentration

~1.6% (active oxygen)

mp

144-147 °C

SMILES string

OS([O-])(=O)=O.[O-]S([O-])(=O)=O.OS(=O)(=O)O[O-].OS(=O)(=O)O[O-].CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC

InChI

1S/5C16H36N.2H2O5S.2H2O4S/c5*1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2*1-5-6(2,3)4;2*1-5(2,3)4/h5*5-16H2,1-4H3;2*1H,(H,2,3,4);2*(H2,1,2,3,4)/q5*+1;;;;/p-5

InChI key

IGMBKNUVZFAHJM-UHFFFAOYSA-I

Application

Reagent for:
  • Oxidation of Hantzsch 1,4-Dihydropyridines catalyzed by manganese(III) Schiff Base complexes
  • Epoxidation of alkenes
  • Oxidation of sulfides and olefins
  • Oxidation of alcohols
  • Oxidation of aromatic amines for synthesis of azoxy arenes

Other Notes

Form of Oxone specially suited for the oxidation of sensitive compounds in CH2Cl2; Reagent for preparing 2-tetrahydrofuranyl ethers from alcohols and THF by radical coupling

Legal Information

OXONE is a registered trademark of E. I. du Pont de Nemours and Company

Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Codes

H302,H314

Hazard Classifications

Acute Tox. 4 Oral - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

PPE (personal protective equipment)

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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