Merck
CN
All Photos(3)

Documents

759546

Sigma-Aldrich

Lithium iron(II) phosphate

greener alternative

powder, <5 μm particle size (BET), >97% (XRF)

Sign Into View Organizational & Contract Pricing
All Photos(3)
Synonym(s):
Ferrous lithium phosphate, Iron lithium phosphate, LFP, Triphylite
Linear Formula:
LiFePO4
CAS Number:
15365-14-7
Molecular Weight:
157.76
NACRES:
NA.23

grade

battery grade

Quality Level

100

Assay

>97% (XRF)

form

powder

mol wt

Mw 157.76 g/mol

composition

LiFePO4

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

particle size

<5 μm (BET)

mp

>300 °C (lit.)

density

3.6 g/cm3 (lit.)

application(s)

battery manufacturing

greener alternative category

Enabling,

InChI

1S/Fe.Li.H3O4P/c;;1-5(2,3)4/h;;(H3,1,2,3,4)/q+2;+1;/p-3

InChI key

GELKBWJHTRAYNV-UHFFFAOYSA-K

Related Categories

General description

Lithium iron(II) phosphate (LiFePO4), also called LFP, is a crystalline, grey-to-black powder with an olivine crystal structure. This unique structure facilitates efficient diffusion of lithium-ions, thanks to the three-dimensional interconnected iron phosphate tetrahedra that form pathways for lithium ions to diffuse. Additionally, the structure is highly stable, not deforming, even after thousands of cycles of lithium intercalation. Our LiFePO4 powder is manufactured to meet high purity with a tightly controlled particle size of less than 5 μm.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Click here for more details.

Application

LiFePO4 is a widely used cathode for rechargeable Li batteries. It has high energy density, wide operating temperature, thermal stability, long cycle life and application life, environmental friendliness, and safety that make it a promising electrode material for greener and safer lithium-ion batteries.

Features and Benefits

LiFePO4-based batteries can last longer, operate safely and reliably, and power devices in a wide range of temperatures.
✔ Achieves 1000s of cycles
✔ Safer than cobalt or manganese-based cathode materials
✔ Reliable performance

Legal Information

Product of Engi-Mat Co.

related product

Product No.
Description
Pricing

442704

Lithium cobalt(III) oxide, 99.8% trace metals basis

746711

Lithium hexafluorophosphate solution, in ethylene carbonate and dimethyl carbonate, 1.0 M LiPF6 in EC/DMC=50/50 (v/v), battery grade

746738

Lithium hexafluorophosphate solution, in ethylene carbonate and ethyl methyl carbonate, 1.0 M LiPF6 in EC/EMC=50/50 (v/v), battery grade

746746

Lithium hexafluorophosphate solution, in ethylene carbonate and diethyl carbonate, 1.0 M LiPF6 in EC/DEC=50/50 (v/v), battery grade

901685

Lithium hexafluorophosphate solution, in ethylene carbonate, dimethyl carbonate and diethyl carbonate, LiPF6 in EC/DMC/DEC=1:1:1 (v/v/v) 1.0 M, battery grade

915432

Lithium manganese nickel oxide, spinel, powder, battery grade

916439

Lithium Manganese Oxide spinel (LMO) powder, battery grade

915173

LATP-coated Lithium Manganese Nickel Oxide (LMNO), powder, battery grade

916196

Carbon coated Lithium Titanate (“LTO”) powder, battery grade

Storage Class Code

11 - Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Documents related to the products that you have purchased in the past have been gathered in the Document Library for your convenience.

Visit the Document Library

Difficulty Finding Your Product Or Lot/Batch Number?

Product numbers are combined with Pack Sizes/Quantity when displayed on the website (example: T1503-25G). Please make sure you enter ONLY the product number in the Product Number field (example: T1503).

Example:

T1503
Product Number
-
25G
Pack Size/Quantity

Additional examples:

705578-5MG-PW

PL860-CGA/SHF-1EA

MMYOMAG-74K-13

1000309185

enter as 1.000309185)

Having trouble? Feel free to contact Technical Service for assistance.

Lot and Batch Numbers can be found on a product's label following the words 'Lot' or 'Batch'.

Aldrich Products

  • For a lot number such as TO09019TO, enter it as 09019TO (without the first two letters 'TO').

  • For a lot number with a filling-code such as 05427ES-021, enter it as 05427ES (without the filling-code '-021').

  • For a lot number with a filling-code such as STBB0728K9, enter it as STBB0728 without the filling-code 'K9'.

Not Finding What You Are Looking For?

In some cases, a COA may not be available online. If your search was unable to find the COA you can request one.

Request COA

Low temperature hydrothermal synthesis of battery grade lithium iron phosphate
Benedek P, et al.
Royal Society of Chemistry Advances, 7(29), 17763-17767 (2017)
Enhanced electrochemical performance of lithium iron (II) phosphate modified cooperatively via chemically reduced graphene oxide and polyaniline
Shen W, et al.
Electrochimica Acta, 173, 310-315 (2015)
P Subramanya Herle et al.
Nature materials, 3(3), 147-152 (2004-03-03)
The provision of efficient electron and ion transport is a critical issue in an exciting new group of materials based on lithium metal phosphates that are important as cathodes for lithium-ion batteries. Much interest centres on olivine-type LiFePO(4), the most
Kim, G. T.; et al.
Journal of Power Sources, 196, 2187-2187 (2011)
Electrochemical noise measurement of a lithium iron (II) phosphate (LiFePO4) rechargeable battery
Astafev E, et al.
Instrumentation Science & Technology, 48(1), 75-85 (2020)
View All Related Papers

Articles

Advances in Conversion-Type Li-Metal Fluoride Battery

Professor Qiao’s laboratory lays out recent advances in conversion type lithium metal fluoride batteries. This review explores key concepts in developing electrochemically stable microstructures for wide Li-ion insertion channels.

Electrode Materials for Lithium Ion Batteries

Solid oxide fuel cells (SOFC) and solid oxide electrolyzers (SOE) are in the early stages of development; however, the performance that has been achieved shows promise for conversion between chemical and electrical energy.

Safer High-performance Electrodes, Solid Electrolytes, and Interface Reactions for Lithium-ion Batteries

Li-ion batteries are currently the focus of numerous research efforts with applications designed to reduce carbon-based emissions and improve energy storage capabilities.

Olivine-Type Cathode Materials for Lithium-Ion Batteries

Lithium-ion batteries (LIBs) have been widely adopted as the most promising portable energy source in electronic devices because of their high working voltage, high energy density, and good cyclic performance.

See All

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service