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Merck
CN

75992

Palladium on activated charcoal

greener alternative

5% Pd, powder

Synonym(s):

Pd/C

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About This Item

Linear Formula:
Pd
UNSPSC Code:
12141733
eCl@ss:
38191001
PubChem Substance ID:
NACRES:
NA.22
MDL number:
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Product Name

Palladium on activated charcoal, 5% Pd basis

SMILES string

[Pd]

InChI

1S/Pd

InChI key

KDLHZDBZIXYQEI-UHFFFAOYSA-N

form

powder

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

greener alternative product characteristics

Designing Safer Chemicals
Catalysis
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concentration

5% Pd

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Quality Level

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Application

Palladium on activated charcoal (Pd/C) is a catalyst used in hydrogenation of alkenes, alkynes, ketones, nitriles, imines, nitro groups, aromatic and heteroaromatic systems. Pd/C also catalyzes phosphination of aryl bromides and triflates with triphenylphines to yield aryl phosphines.
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pictograms

Flame

signalword

Danger

hcodes

Hazard Classifications

Flam. Sol. 1

Storage Class

4.1B - Flammable solid hazardous materials

wgk

WGK 3

ppe

Eyeshields, Gloves, type N95 (US)


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Examination of the aromatic amination catalyzed by palladium on charcoal.
Komaromi, Anna and Novak, Zoltan
Advanced Synthesis & Catalysis, 352(9), 1523-1532 (2010)
Examination of the aromatic amination catalyzed by palladium on charcoal.
Komaromi, Anna and Novak, Zoltan
advanced synthesis and catalysis, 352(9), 1523-1532 (2010)
Palladium on Carbon.
eEROS (Encyclopedia of Reagents for Organic Synthesis) (2001)
Synthesis of aryl phosphines by phosphination with triphenylphosphine catalyzed by palladium on charcoal.
Lai, Chi Wai et al.
Tetrahedron Letters, 42(29), 4883-4885 (2001)
Sonogashira coupling of aryl halides catalyzed by palladium on charcoal.
Novak, Zoltan et al.
The Journal of Organic Chemistry, 68(8), 3327-3329 (2003)

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