76050
Palladium(II) chloride
anhydrous, 60% Pd, solid
Synonym(s):
Dichloropalladium, Palladium dichloride, Palladous chloride
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About This Item
Product Name
Palladium(II) chloride, anhydrous, 60% Pd basis
Quality Segment
form
solid
reaction suitability
core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: inorganic catalyst
concentration
60% Pd
mp
678-680 °C (lit.)
density
4 g/mL at 25 °C (lit.)
SMILES string
Cl[Pd]Cl
InChI
1S/2ClH.Pd/h2*1H;/q;;+2/p-2
InChI key
PIBWKRNGBLPSSY-UHFFFAOYSA-L
Application
- Cross-coupling reactions between terminal alkynes and aryl iodides or bromides under modified Sonogashira-Cassar-Heck conditions.
- Carbonylation of organic tellurides with carbon monoxide to form corresponding methyl carboxylates.
- Isomerization of allylic ester in acetic acid.
- Carbonylation of amines to form isocyanates.
Used in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.
Other Notes
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Signal Word
Danger
Hazard Codes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Skin Sens. 1
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
PPE (personal protective equipment)
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Precautionary Statements
Storage Class
13 - Non Combustible Solids
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