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Merck
CN

76063

Palladium hydroxide on activated charcoal

greener alternative

10-20% Pd (based on dry substance), lumps, moistened with water

Synonym(s):

Pd(OH)2/C, Pearlman’s catalysts

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About This Item

UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
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Product Name

Palladium hydroxide on activated charcoal, moistened with water, 10-20% Pd basis (based on dry substance)

Quality Level

form

lumps

quality

moistened with water

contains

~50% water as stabilizer

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

greener alternative product characteristics

Designing Safer Chemicals
Catalysis
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sustainability

Greener Alternative Product

concentration

10-20% Pd (based on dry substance)

greener alternative category

SMILES string

O[Pd]O

InChI

1S/2H2O.Pd/h2*1H2;/q;;+2/p-2

InChI key

NXJCBFBQEVOTOW-UHFFFAOYSA-L

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalysis. Click here for more information.

Application

Catalyst for hydrogenolysis of benzyl groups and epoxides; used to reduce nitro compounds to amines and as dehydrogenation reagent.
Hydrogenation catalyst


pictograms

Environment

signalword

Warning

hcodes

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves



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Jung, M. E.; Choi, Y. M.
The Journal of Organic Chemistry, 56, 6729-6729 (1991)
Zhao, S.; Freeman, J. P.; Szmuszkovicz, J.
The Journal of Organic Chemistry, 57, 4051-4051 (1992)
Prugh, J. D.; Rooney, C. S. et al.
Tetrahedron Letters, 26, 2947-2947 (1985)



Global Trade Item Number

SKUGTIN
76063-50G04061833449226
76063-5G04061833358962