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Merck
CN

76063

Palladium hydroxide on activated charcoal

greener alternative

10-20% Pd (based on dry substance), lumps, moistened with water

Synonym(s):

Pd(OH)2/C, Pearlman’s catalysts

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About This Item

UNSPSC Code:
12161600
PubChem Substance ID:
57652615
NACRES:
NA.22
MDL number:
MFCD00064599

Key Documents

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Product Name

Palladium hydroxide on activated charcoal, moistened with water, 10-20% Pd basis (based on dry substance)

SMILES string

O[Pd]O

InChI

1S/2H2O.Pd/h2*1H2;/q;;+2/p-2

InChI key

NXJCBFBQEVOTOW-UHFFFAOYSA-L

form

lumps

quality

moistened with water

contains

~50% water as stabilizer

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

greener alternative product characteristics

Designing Safer Chemicals
Catalysis
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sustainability

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concentration

10-20% Pd (based on dry substance)

greener alternative category

Aligned

Quality Level

100

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalysis. Click here for more information.

Application

Catalyst for hydrogenolysis of benzyl groups and epoxides; used to reduce nitro compounds to amines and as dehydrogenation reagent.
Hydrogenation catalyst

pictograms

Environment
GHS09

signalword

Warning

hcodes

H410

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCP0808
BCCK5041
1332670V
1332670
1171763

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Jung, M. E.; Choi, Y. M.
The Journal of Organic Chemistry, 56, 6729-6729 (1991)
Zhao, S.; Freeman, J. P.; Szmuszkovicz, J.
The Journal of Organic Chemistry, 57, 4051-4051 (1992)
Prugh, J. D.; Rooney, C. S. et al.
Tetrahedron Letters, 26, 2947-2947 (1985)
Development of GSKDevelopment of GSK's reagent guides ? embedding sustainability into reagent selections reagent guides ? embedding sustainability into reagent selection.
Adams JP, et al.
Green Chemistry, 15, 1542-1549 (2013)

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