761435
[(二(1-金刚烷基)丁基膦基)-2-(2′-氨基-1,1′-联苯基)]钯(II)甲磺酸酯
95%, solid
别名:
[(二(1-金刚烷基)丁基膦基)-2-(2′-氨基-1,1′-联苯基)]钯(II) 甲磺酸酯, cataCXium-A-Pd-G3, 甲磺酸[(二(1-金刚烷基)丁基膦基)-2-(2′-氨基-1,1′-联苯基)]钯(II)
选择规格
关于此项目
产品名称
[(二(1-金刚烷基)丁基膦基)-2-(2′-氨基-1,1′-联苯基)]钯(II)甲磺酸酯, 95%
product line
Buchwald precatalyst Generation 3
Quality Segment
assay
95%
form
solid
feature
generation 3
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplings
greener alternative product score
old score: 16
new score: 2
Find out more about DOZN™ Scoring
greener alternative product characteristics
Waste Prevention
Atom Economy
Safer Solvents and Auxiliaries
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
impurities
≤3% acetone
mp
196-241 °C (decomposition)
functional group
phosphine
greener alternative category
SMILES string
CS(=O)(=O)O[Pd]c1ccccc1-c2ccccc2N.CCCCP([C@@]34C[C@@H]5C[C@@H](C[C@@H](C5)C3)C4)[C@@]67C[C@@H]8C[C@@H](C[C@@H](C8)C6)C7
InChI
1S/C24H39P.C12H10N.CH4O3S.Pd/c1-2-3-4-25(23-11-17-5-18(12-23)7-19(6-17)13-23)24-14-20-8-21(15-24)10-22(9-20)16-24;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h17-22H,2-16H2,1H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1/t17-,18+,19-,20-,21+,22-,23-,24-;;;
InChI key
REYVZCOGMIXVNX-DVBMAMJVSA-M
General description
Application
- 吡啶羧酸的直接邻位芳基化。
- 催化Suzuki–Miyaura交叉偶联反应，以合成1-杂芳基-3-氮杂双环[3.1.0]己烷。
- 炔烃的钯催化羰基碳全氟烷基化。
- 各种 gem二取代环丙烷的合成过程中成对二(溴基)环丙烷的Suzuki–Miyaura 偶联反应。
- 末端炔烃的溴全氟烷基化。
- 芳香卤化物和炔烃的无铜Sonogashira 偶联反应，以形成 C-C键。
- 有机三氟硼酸盐和芳基卤化物的Suzuki 交叉偶联反应。
Legal Information
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable