762229
tBuXPhos Pd G3
98%, solid
Synonym(s):
tBuXPhos-Pd-G3, [(2-Di-tert-butylphosphino-2′,4′,6′-triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′-biphenyl)] palladium(II) methanesulfonate
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About This Item
Product Name
tBuXPhos Pd G3, 98%
SMILES string
CS(=O)(=O)O[Pd]c1ccccc1-c2ccccc2N.CC(C)c3cc(C(C)C)c(c(c3)C(C)C)-c4ccccc4P(C(C)(C)C)C(C)(C)C
InChI
1S/C29H45P.C12H10N.CH4O3S.Pd/c1-19(2)22-17-24(20(3)4)27(25(18-22)21(5)6)23-15-13-14-16-26(23)30(28(7,8)9)29(10,11)12;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h13-21H,1-12H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1
InChI key
SQQOHCLJPLSJGX-UHFFFAOYSA-M
Quality Level
product line
Buchwald precatalyst Generation 3
assay
98%
form
solid
feature
generation 3
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplings
mp
130-140 °C
functional group
phosphine
Application
For small scale and high throughput uses, product is also available as ChemBeads (931055)
General description
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Articles
All contents in the foil bag are weighed, plated, packed, and sealed in a glove box under nitrogen.
G3 and G4 Buchwald palladium precatalysts are the newest air, moisture, and thermally stable crossing-coupling complexes used in bond formation for their versatility and high reactivity.
Preformed catalysts in the kit are stable but become air-sensitive when activated; Schlenk technique aids scale-up.
Preformed catalysts in the kit are stable but become air-sensitive when activated; Schlenk technique aids scale-up.
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