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Merck
CN

762776

1,12-Bis((1-methylbenzimidazolium)-3-yl)dodecane dibromide

97%

Synonym(s):

3,3′-(Dodecane-1,12-diyl)bis(1-methyl-1H-benzo[d]imidazol-3-ium) bromide

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About This Item

Empirical Formula (Hill Notation):
C28H40Br2N4
Molecular Weight:
592.45
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
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assay

97%

form

solid

reaction suitability

reagent type: catalyst

mp

192-197 °C

SMILES string

[Br-].[Br-].Cn1c[n+](CCCCCCCCCCCC[n+]2cn(C)c3ccccc23)c4ccccc14

InChI

1S/C28H40N4.2BrH/c1-29-23-31(27-19-13-11-17-25(27)29)21-15-9-7-5-3-4-6-8-10-16-22-32-24-30(2)26-18-12-14-20-28(26)32;;/h11-14,17-20,23-24H,3-10,15-16,21-22H2,1-2H3;2*1H/q+2;;/p-2

InChI key

JYLHYZQULXGKCH-UHFFFAOYSA-L

Application

Highly efficient catalyst for the benzoin reaction


Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



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Ken-ichi Iwamoto et al.
Organic & biomolecular chemistry, 6(5), 912-915 (2008-02-23)
Benzoin reactions are catalyzed effectively by a methylene-bridged bis(benzimidazolium) salt to yield alpha-hydroxy ketones, and the reactions proceed in water as the aqueous medium under mild conditions.



Global Trade Item Number

SKUGTIN
762776-1G04061826654422
762776-5G04061833340264