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762830

JackiePhos Pd G3

Name: JackiePhos Pd G3
Brand: ALDRICH

95%, solid

Synonym(s):

JackiePhos-Pd-G3, [(2-{Bis[3,5-bis(trifluoromethyl)phenyl]phosphine}-3,6-dimethoxy- 2′,4′,6′- triisopropyl-1,1′-biphenyl )-2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate

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About This Item

Empirical Formula (Hill Notation):

C₅₂H₅₀F₁₂NO₅PPdS

CAS Number:

2102544-35-2

Molecular Weight:

1166.40

UNSPSC Code:

12161600

PubChem Substance ID:

329767007

NACRES:

NA.22

MDL number:

MFCD22572672

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Properties

Product Name

JackiePhos Pd G3, 95%

Quality Level

100

product line

Buchwald precatalyst Generation 3

assay

95%

form

solid

feature

generation 3

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplings

mp

195-197 °C (decomposition)

functional group

phosphine

SMILES string

CS(=O)(=O)O[Pd]c1ccccc1-c2ccccc2N.COc3ccc(OC)c(c3P(c4cc(cc(c4)C(F)(F)F)C(F)(F)F)c5cc(cc(c5)C(F)(F)F)C(F)(F)F)-c6c(cc(cc6C(C)C)C(C)C)C(C)C

InChI

1S/C39H37F12O2P.C12H10N.CH4O3S.Pd/c1-19(2)22-11-29(20(3)4)33(30(12-22)21(5)6)34-31(52-7)9-10-32(53-8)35(34)54(27-15-23(36(40,41)42)13-24(16-27)37(43,44)45)28-17-25(38(46,47)48)14-26(18-28)39(49,50)51;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h9-21H,1-8H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1

InChI key

LLXGRQGGARSAOC-UHFFFAOYSA-M

Description

Application

JackiePhos Pd G3 can be used as a palladium precatalyst in Stille cross-coupling reaction between organostannane and ary halides.

Storage Class

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable

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Global Trade Item Number

SKU	GTIN
762830-1G	04061826252024
762830-5G	04061832970721
762830-100MG	04061832970707
762830-500MG	04061832970714