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Merck
CN

763551

Pentaerythritol tetrakis[2-(dodecylthiocarbonothioylthio)-2-methylpropionate]

97% (HPLC)

Synonym(s):

4 arm start DDMAT RAFT agent

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About This Item

Empirical Formula (Hill Notation):
C73H132O8S12
Molecular Weight:
1522.60
NACRES:
NA.23
PubChem Substance ID:
329767062
UNSPSC Code:
12352100
MDL number:
MFCD22666445

Key Documents

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Product Name

Pentaerythritol tetrakis[2-(dodecylthiocarbonothioylthio)-2-methylpropionate], 97% (HPLC)

InChI

1S/C73H132O8S12/c1-13-17-21-25-29-33-37-41-45-49-53-86-65(82)90-69(5,6)61(74)78-57-73(58-79-62(75)70(7,8)91-66(83)87-54-50-46-42-38-34-30-26-22-18-14-2,59-80-63(76)71(9,10)92-67(84)88-55-51-47-43-39-35-31-27-23-19-15-3)60-81-64(77)72(11,12)93-68(85)89-56-52-48-44-40-36-32-28-24-20-16-4/h13-60H2,1-12H3

SMILES string

CCCCCCCCCCCCSC(=S)SC(C)(C)C(=O)OCC(COC(=O)C(C)(C)SC(=S)SCCCCCCCCCCCC)(COC(=O)C(C)(C)SC(=S)SCCCCCCCCCCCC)COC(=O)C(C)(C)SC(=S)SCCCCCCCCCCCC

InChI key

ONXYMIIQXBMPMD-UHFFFAOYSA-N

assay

97% (HPLC)

form

solid

mp

30-34 °C

storage temp.

2-8°C

Quality Level

100

Related Categories

Application

Reversible Addition Fragmentation Chain Transfer (RAFT) Polymerization

General description

Functionalized RAFT agent for controlled radical polymerization; especially suited for the polymerization of styrene; acrylate and acrylamide monomers. For use in advanced material (rheology; etc) and biomaterial (nanomedicine) applications. Chain Transfer Agent (CTA)
Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCZ4904
MKCN5007
MKBL1527

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Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being

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Protein- and Peptide- Polymer Conjugates by RAFT Polymerization

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

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