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Merck
CN

767727

Chloro(5-methoxy-2-{1-[(4-methoxyphenyl)imino-N]ethyl}phenyl-C)(1,2,3,4,5-pentamethylcyclopentadienyl)iridium(III)

greener alternative

97%, solid

Synonym(s):

Chloro[5-methoxy-2-[1-[(4-methoxyphenyl)imino-N]ethyl]phenyl- C][(1,2,3,4,5-η)-1,2,3,4,5-pentamethyl-2,4-cyclopenta dien-1-yl]iridium

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About This Item

Empirical Formula (Hill Notation):
C26H31ClIrNO2
CAS Number:
Molecular Weight:
617.20
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
EC Number:
200-838-9
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Product Name

Chloro(5-methoxy-2-{1-[(4-methoxyphenyl)imino-N]ethyl}phenyl-C)(1,2,3,4,5-pentamethylcyclopentadienyl)iridium(III), 97%

InChI

1S/C16H16NO2.C5H5.ClH.Ir/c1-12(13-4-8-15(18-2)9-5-13)17-14-6-10-16(19-3)11-7-14;1-2-4-5-3-1;;/h4,6-11H,1-3H3;1-5H;1H;/q;;;+1/p-1/b17-12+;;;

InChI key

JZDNDPJBPBFFCT-DPSBJRLESA-M

SMILES string

[CH]1[CH][CH][CH][CH]1.COc2ccc(cc2)\N=C(/C)c3ccc(OC)cc3[Ir]Cl

assay

97%

form

solid

reaction suitability

core: iridium, reagent type: catalyst

greener alternative product characteristics

Catalysis
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sustainability

Greener Alternative Product

impurities

~1% Dichloromethane

mp

200-239 °C

greener alternative category

Quality Level

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Catalyst for reductive amination by transfer hydrogenation.

pictograms

Health hazard

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Warning

hcodes

Hazard Classifications

Carc. 2

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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A versatile catalyst for reductive amination by transfer hydrogenation.
Chao Wang et al.
Angewandte Chemie (International ed. in English), 49(41), 7548-7552 (2010-11-03)

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