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Merck
CN

769495

Cobalt(II) chloride hexahydrate

≥97%

Synonym(s):

Cobaltous chloride hexahydrate

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About This Item

Linear Formula:
CoCl2 · 6H2O
CAS Number:
Molecular Weight:
237.93
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
231-589-4
MDL number:
Assay:
≥97%, 97.0-102.0% (KT)
Form:
solid
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vapor pressure

40 mmHg ( 0 °C)

Quality Level

assay

≥97%, 97.0-102.0% (KT)

form

solid

reaction suitability

core: cobalt

anion traces

nitrate (NO3-): ≤0.01%, sulfate (SO42-): ≤0.007%

cation traces

Fe: ≤0.005%, Ni: ≤0.15%, Pb: ≤0.002%, Zn: ≤0.05%

application(s)

battery precursors
catalysts
material synthesis precursor

SMILES string

O.O.O.O.O.O.Cl[Co]Cl

InChI

1S/2ClH.Co.6H2O/h2*1H;;6*1H2/q;;+2;;;;;;/p-2

InChI key

GFHNAMRJFCEERV-UHFFFAOYSA-L

General description

Cobalt(II) chloride hexahydrate, a hydrated form of cobalt chloride, is employed in electroplating and catalyst preparation. It serves as a precursor for synthesizing electrode materials for lithium-ion batteries and acts as a catalyst in a range of organic reactions, including acetylation, tosylation of alcohols, and condensation reactions.

Application

Cobalt(II) chloride hexahydrate can be used as:      
  • An additive to the electron transport layer (ETL) in perovskite solar cells to improve their performance, particularly by reducing energy losses and increasing the open-circuit voltage.      
  • A cobalt source for doping ZnO nanostructures. The incorporation of cobalt ions into the ZnO matrix is crucial for modifying its electronic and optical properties.      
  • A precursor to modify cobalt metal-organic framework (Co-MOF) derived carbon microspheres for application as anode materials in lithium-ion batteries.

Analysis Note

Substances not precipitated by ammonium sulfide (as sulphates) ≤ 0.3 %


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Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B Inhalation - Eye Dam. 1 - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Sens. 1

Storage Class

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

危险化学品

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One-step synthesis of cobalt and nitrogen co-doped carbon nanotubes and their catalytic activity for the oxygen reduction reaction
Fu, S., et al.
Journal of Material Chemistry A, 3, 12718-12722 (2015)
Hyeohn Kim et al.
ACS nano, 15(1), 979-988 (2020-12-18)
Chiral inorganic nanomaterials have revealed opportunities in various fields owing to their strong light-matter interactions. In particular, chiral metal oxide nanomaterials that can control light and biochemical reactions have been highlighted due to their catalytic activity and biocompatibility. In this
Excellent lithium ion storage property of porous MnCo2O4 nanorods
Zeng, P., et al.
Royal Society of Chemistry Advances, 6, 23074-23084 (2016)



Global Trade Item Number

SKUGTIN
769495-100G04061833315019