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About This Item
Linear Formula:
CF3(CF2)7SO3H
CAS Number:
Molecular Weight:
500.13
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1813859
Form:
liquid
form
liquid
concentration
~40% in H2O (T)
functional group
fluoro, sulfonic acid
SMILES string
OS(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F
InChI
1S/C8HF17O3S/c9-1(10,3(13,14)5(17,18)7(21,22)23)2(11,12)4(15,16)6(19,20)8(24,25)29(26,27)28/h(H,26,27,28)
InChI key
YFSUTJLHUFNCNZ-UHFFFAOYSA-N
Application
Heptadecafluorooctanesulfonic acid solution can be used as a catalyst:
- In the benzoylation of a variety of unactivated benzenes via Friedel-Crafts acylation reaction in the presence of rare earth(III) perfluorooctane sulfonate in fluorous solvents.
- For the dinitration of aromatic compounds to synthesize dinitrobenzenes in the presence of ytterbium perfluorooctane sulfonate and fluorous solvent.
- To synthesize tetrahydroisoquinoline derivatives via Pictet-Spengler reaction of β-arylethyl carbamates with aldehydes.
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signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 2 - Carc. 2 - Lact. - Repr. 1B - STOT RE 1
Storage Class
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Regulatory Information
监管及禁止进口产品
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Highly efficient dinitration of aromatic compounds in fluorous media using ytterbium perfluorooctanesulfonate and perfluorooctanesulfonic acid as catalysts
Yi W, et al.
Synthetic Communications, 36, 2957-2961 (2006)
Pictet-Spengler reactions catalyzed by Bronsted acid-surfactant-combined catalyst in water or aqueous media
Saito A, et al.
Tetrahedron Letters, 48, 835-839 (2007)
Rare earth (III) perfluorooctane sulfonates and perfluorooctanesulfonic acid in fluorous solvents: Novel and recyclable catalytic systems for Friedel-Crafts acylation of unactivated benzenes
Yi W, et al.
Journal of Fluorine Chemistry, 126, 1191-1195 (2005)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 77283-50ML | 04061837250286 |
| 77283-10ML | 04061832930725 |


