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Merck
CN

773522

tert-Butylmagnesium chloride solution

greener alternative
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About This Item

Linear Formula:
(CH3)3CMgCl
CAS Number:
677-22-5
Molecular Weight:
116.87
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
329767623
MDL number:
MFCD00000465
Beilstein/REAXYS Number:
3535403

Key Documents

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InChI key

ZDRJSYVHDMFHSC-UHFFFAOYSA-M

SMILES string

CC(C)(C)[Mg]Cl

InChI

1S/C4H9.ClH.Mg/c1-4(2)3;;/h1-3H3;1H;/q;;+1/p-1

form

solution

reaction suitability

reaction type: Grignard Reaction

greener alternative product characteristics

Safer Solvents and Auxiliaries
Use of Renewable Feedstocks
Inherently Safer Chemistry for Accident Prevention
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

density

0.878 g/mL at 25 °C

greener alternative category

, Aligned

Quality Level

100

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Application

Grignard reagent has been utilized in nucleophilic additions and substitutions; metal-halogen exchanges and Kumada couplings.
Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product, 1.0 M in 2-methyltetrahydrofuran aligns with "Safer Solvents and Auxiliaries", "Use of Renewable Feedstocks" and "Inherently Safer Chemistry for Accident Prevention". Find details here.

Packaging

The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

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Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Skin Corr. 1B - Water-react 1

supp_hazards

EUH019

Storage Class

4.2 - Pyrophoric and self-heating hazardous materials

wgk

WGK 3

flash_point_f

-22.0 °F

flash_point_c

-30 °C

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
SHBG1494V
SHBD3938V
SHBD0064V
SHBC7784

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