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Merck
CN

778362

5-Methyl-5-allyloxycarbonyl-1,3-dioxan-2-one

97%

Synonym(s):

5-Methyl-2-oxo-1,3-dioxane-5-carboxylic acid, 2-propen-1-yl ester, Allyl 5-methyl-2-oxo-1,3-dioxane-5-carboxylate, Allyl functionalized carbonate monomer, MAC

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About This Item

Empirical Formula (Hill Notation):
C9H12O5
CAS Number:
532424-75-2
Molecular Weight:
200.19
NACRES:
NA.23
PubChem Substance ID:
329767961
UNSPSC Code:
12162002
MDL number:
MFCD26142783

Key Documents

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Product Name

5-Methyl-5-allyloxycarbonyl-1,3-dioxan-2-one, 97%

InChI

1S/C9H12O5/c1-3-4-12-7(10)9(2)5-13-8(11)14-6-9/h3H,1,4-6H2,2H3

SMILES string

O=C1OCC(C(OCC=C)=O)(C)CO1

InChI key

OPWZLMZGHGAFNG-UHFFFAOYSA-N

assay

97%

form

solid

mp

65-70 °C

storage temp.

−20°C

Application

This monomer contains a pendant allyl group for thiol-ene click chemistry; to be copolymerized with lactides or glycolides for biodegradable polymers containing pendant functional groups.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCJ0872
MKBP5872

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Nerve Zhou et al.
PloS one, 12(3), e0173318-e0173318 (2017-03-11)
The Crabtree positive yeasts, such as Saccharomyces cerevisiae, prefer fermentation to respiration, even under fully aerobic conditions. The selective pressures that drove the evolution of this trait remain controversial because of the low ATP yield of fermentation compared to respiration.
Kanwal Ashraf et al.
Molecular biology and evolution, 36(5), 1037-1055 (2019-02-24)
Epigenetic information, which can be passed on independently of the DNA sequence, is stored in part in the form of histone posttranslational modifications and specific histone variants. Although complexes necessary for deposition have been identified for canonical and variant histones
M Coburn et al.
British journal of anaesthesia, 120(1), 127-137 (2018-02-06)
Postoperative delirium occurs frequently in elderly hip fracture surgery patients and is associated with poorer overall outcomes. Because xenon anaesthesia has neuroprotective properties, we evaluated its effect on the incidence of delirium and other outcomes after hip fracture surgery. This
D J Eleveld et al.
British journal of anaesthesia, 120(5), 942-959 (2018-04-18)
Pharmacokinetic (PK) and pharmacodynamic (PD) models are used in target-controlled-infusion (TCI) systems to determine the optimal drug administration to achieve a desired target concentration in a central or effect-site compartment. Our aim was to develop a PK-PD model for propofol
Lifang Feng et al.
Nucleic acids research, 45(16), 9481-9502 (2017-09-22)
Developmentally programmed genome rearrangement accompanies differentiation of the silent germline micronucleus into the transcriptionally active somatic macronucleus in the ciliated protozoan Tetrahymena thermophila. Internal eliminated sequences (IES) are excised, followed by rejoining of MAC-destined sequences, while fragmentation occurs at conserved
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