78055
L-Phenylalanine allyl ester p-toluenesulfonate salt
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About This Item
Empirical Formula (Hill Notation):
C12H15NO2 · C7H8O3S
CAS Number:
Molecular Weight:
377.45
Beilstein:
5212778
MDL number:
UNSPSC Code:
12352200
PubChem Substance ID:
optical activity
[α]20/D +10.5±1°, c = 1% in DMF
mp
155-158 °C
application(s)
peptide synthesis
SMILES string
Cc1ccc(cc1)S(O)(=O)=O.N[C@@H](Cc2ccccc2)C(=O)OCC=C
InChI
1S/C12H15NO2.C7H8O3S/c1-2-8-15-12(14)11(13)9-10-6-4-3-5-7-10;1-6-2-4-7(5-3-6)11(8,9)10/h2-7,11H,1,8-9,13H2;2-5H,1H3,(H,8,9,10)/t11-;/m0./s1
InChI key
PKXPRZFLCJFMHN-MERQFXBCSA-N
Other Notes
Used in peptide and N-glycopeptide synthesis; the ester is selectively deblocked with (Ph3P)3RhCl
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H. Waldmann et al.
Liebigs Ann. Chem., 1712-1712 (1983)
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