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Merck
CN

78175

N-Phenyl-bis(trifluoromethanesulfonimide)

≥98.0% (HPLC)

Synonym(s):

1,1,1-Trifluoro-N-phenyl-N-[(trifluoromethyl)sulfonyl]methanesulfonamide, N,N-Bis(trifluoromethylsulfonyl)aniline, N-Phenyl-trifluoromethanesulfonimide, NSC 240874, Phenyl triflimide

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About This Item

Linear Formula:
C6H5N(SO2CF3)2
CAS Number:
37595-74-7
Molecular Weight:
357.25
UNSPSC Code:
12352002
NACRES:
NA.22
PubChem Substance ID:
57652731
MDL number:
MFCD00000404
Beilstein/REAXYS Number:
1269141
Assay:
≥98.0% (HPLC)
Form:
crystals

Key Documents

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InChI

1S/C8H5F6NO4S2/c9-7(10,11)20(16,17)15(6-4-2-1-3-5-6)21(18,19)8(12,13)14/h1-5H

SMILES string

FC(F)(F)S(=O)(=O)N(c1ccccc1)S(=O)(=O)C(F)(F)F

InChI key

DIOHEXPTUTVCNX-UHFFFAOYSA-N

assay

≥98.0% (HPLC)

form

crystals

Quality Level

200

functional group

fluoro

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Application

Acts as a transparent strong electron-withdrawing p-type dopant in carbon nanotubes

Reactant for:
Synthesis of amphoteric alpha-boryl aldehydes
Enantioselective synthesis of core ring skeleton of leucosceptroids A-D
Stereoselective synthesis of monoamine reuptake inhibitor NS9544 acetate
Stereoselective sulfoxidation

Other Notes

Stable, crystalline and easy-to-handle triflating agent, useful for the triflation of phenols and amines (especially aliphatic secondary amines; aromatic secondary amines do not react); For the preparation of triflones; For the preparation of enol triflates from ketones

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
BCCD0584
BCCK3832
BCBV4281
BCBJ5844V
BCBF1445V

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Find documentation for the products that you have recently purchased in the Document Library.

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J.B. Hendrickson et al.
Tetrahedron, 31, 2517-2517 (1975)
J.B. Hendrickson et al.
The Journal of Organic Chemistry, 42, 3875-3875 (1977)
W.J. Scott et al.
Accounts of Chemical Research, 21, 47-47 (1988)

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