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Merck
CN

791105

Zinc chloromethanesulfinate

95% (H-NMR)

Synonym(s):

Baran MCMS Reagent

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About This Item

Empirical Formula (Hill Notation):
C2H4Cl2O4S2Zn
CAS Number:
Molecular Weight:
292.48
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352101
MDL number:
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Product Name

Zinc chloromethanesulfinate, 95% (H-NMR)

InChI

1S/2CH3ClO2S.Zn/c2*2-1-5(3)4;/h2*1H2,(H,3,4);/q;;+2/p-2

SMILES string

ClCS(O[Zn]OS(CCl)=O)=O

InChI key

HEKATMPPXNXYJU-UHFFFAOYSA-L

assay

95% (H-NMR)

form

solid

reaction suitability

reaction type: C-C Bond Formation
reagent type: catalyst
reaction type: C-H Activation

reagent type: diversification reagent

mp

190-195 °C

functional group

chloro
sulfinic acid

storage temp.

2-8°C

Quality Level

Application

Zinc chloromethanesulfinate (MCMS) is part of a zinc sulfinate toolbox developed by Phil Baran for the simple and rapid diversification of heterocycles.1

Practical and Innate Carbon-Hydrogen Functionalization of Heterocycles

Learn More at the Professor and Product Portal of Professor Phil S. Baran.

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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Journal of the American Chemical Society
O'Hara,F.; et. al.
Journal of the American Chemical Society, 135, 12122-12134 null
Practical and Innate Carbon-Hydrogen Functionalization of Heterocycles
Fujiwara, Y.; et al.
Nature, 492, 95-100 (2013)

Articles

Rapidly diversify (hetero)aromatic scaffolds for chemical industry needs amid resource and time constraints, ensuring efficiency.

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