794279
Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II)
solid
Synonym(s):
Buchwald Nickel Cross-Coupling Catalyst Precursor, [Bis(triphenylphosphine)](o-tolyl)chloronickel
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About This Item
Product Name
Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II),
form
solid
Quality Level
reaction suitability
core: nickel
reagent type: catalyst
mp
195-200 °C
storage temp.
2-8°C
SMILES string
Cl[Ni]C1=CC=CC=C1C.P(C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4.P(C5=CC=CC=C5)(C6=CC=CC=C6)C7=CC=CC=C7
InChI
1S/2C18H15P.C7H7.ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;;/h2*1-15H;2-5H,1H3;1H;/q;;;;+1/p-1
InChI key
QVGJKVLYWZGANE-UHFFFAOYSA-M
Related Categories
Application
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Carc. 1B - Skin Sens. 1
Storage Class Code
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Articles
Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.
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