796549
Stahl Aerobic Oxidation TEMPO solution
0.2 M in acetonitrile, Solution for Oxidation of Primary Alcohols
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About This Item
Quality Segment
form
liquid
reaction suitability
reagent type: oxidant
concentration
0.2 M in acetonitrile
storage temp.
2-8°C
SMILES string
CN1C=CN=C1.CC2(C)CCCC(C)(C)N2[O].C3(C4=NC=CC=C4)=NC=CC=C3
InChI
1S/C10H8N2.C9H18NO.C4H6N2/c1-3-7-11-9(5-1)10-6-2-4-8-12-10;1-8(2)6-5-7-9(3,4)10(8)11;1-6-3-2-5-4-6/h1-8H;5-7H2,1-4H3;2-4H,1H3
InChI key
BQFURWVGIDXRNB-UHFFFAOYSA-N
General description
Stahl Aerobic Oxidation TEMPO solution contains 1-methylimidazole (NMI), 2,2′-bipyridyl (bpy), and TEMPO. It is widely employed for the oxidation of alcohols.
Application
This convenience solution can be used in tandem with tetrakisacetonitrile copper(I) triflate (685038) for the oxidation of primary alcohols through aerobic conditions developed by the Stahl Research Group.
signalword
Danger
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1C
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
35.6 °F
flash_point_c
2.0 °C
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