805041
2-(三甲硅基)-2-环己烯-1-酮
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关于此项目
经验公式（希尔记法）:
C9H16OSi
化学文摘社编号:
分子量:
168.31
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Form:
liquid
description
Fp: 15.8°F
Quality Segment
form
liquid
refractive index
n20/D 1.4524
density
0.8680 g/mL at 25 °C
functional group
ketone
storage temp.
−20°C
SMILES string
O=C1C([Si](C)(C)C)=CCCC1
InChI
1S/C9H16OSi/c1-11(2,3)9-7-5-4-6-8(9)10/h7H,4-6H2,1-3H3
InChI key
SXGCQSJRVVKTOH-UHFFFAOYSA-N
General description
2-(Trimethylsilyl)-2-cyclohexen-1-one is a silyl enone.
Application
The following silyl enone can be converted into a highly useful cyclohexyne precursor as reported by the Garg and DuBois groups. The resulting silyltriflate adduct can be subjected to various dienes and dipolarophiles in the presence of Cesium Fluoride.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Flam. Sol. 2
存储类别
4.1B - Flammable solid hazardous materials
wgk
WGK 3
flash_point_f
15.8 °F
flash_point_c
-9 °C