805041
2-(trimethylsilyl)-2-cyclohexen-1-one
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About This Item
Empirical Formula (Hill Notation):
C9H16OSi
CAS Number:
Molecular Weight:
168.31
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
description
Fp: 15.8°F
Quality Level
form
liquid
refractive index
n20/D 1.4524
density
0.8680 g/mL at 25 °C
functional group
ketone
storage temp.
−20°C
SMILES string
O=C1C([Si](C)(C)C)=CCCC1
InChI
1S/C9H16OSi/c1-11(2,3)9-7-5-4-6-8(9)10/h7H,4-6H2,1-3H3
InChI key
SXGCQSJRVVKTOH-UHFFFAOYSA-N
Related Categories
General description
2-(Trimethylsilyl)-2-cyclohexen-1-one is a silyl enone.
Application
The following silyl enone can be converted into a highly useful cyclohexyne precursor as reported by the Garg and DuBois groups. The resulting silyltriflate adduct can be subjected to various dienes and dipolarophiles in the presence of Cesium Fluoride.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Flam. Sol. 2
Storage Class Code
4.1B - Flammable solid hazardous materials
WGK
WGK 3
Flash Point(F)
15.8 °F
Flash Point(C)
-9 °C
Regulatory Information
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