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经验公式(希尔记法):
C9H16OSi
化学文摘社编号:
分子量:
168.31
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Form:
liquid
InChI
1S/C9H16OSi/c1-11(2,3)9-7-5-4-6-8(9)10/h7H,4-6H2,1-3H3
SMILES string
O=C1C([Si](C)(C)C)=CCCC1
InChI key
SXGCQSJRVVKTOH-UHFFFAOYSA-N
description
Fp: 15.8°F
form
liquid
refractive index
n20/D 1.4524
density
0.8680 g/mL at 25 °C
functional group
ketone
storage temp.
−20°C
Quality Level
General description
2-(Trimethylsilyl)-2-cyclohexen-1-one is a silyl enone.
Application
The following silyl enone can be converted into a highly useful cyclohexyne precursor as reported by the Garg and DuBois groups. The resulting silyltriflate adduct can be subjected to various dienes and dipolarophiles in the presence of Cesium Fluoride.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Flam. Sol. 2
存储类别
4.1B - Flammable solid hazardous materials
wgk
WGK 3
flash_point_f
15.8 °F
flash_point_c
-9 °C
法规信息
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