80631
Sodium bis(trimethylsilyl)amide solution
40% in THF
Synonym(s):
HMN-Na Sol, NaHMDS solution, Hexamethyldisilazane sodium salt solution
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About This Item
Product Name
Sodium bis(trimethylsilyl)amide solution, 40% in THF
InChI
1S/C6H18NSi2.Na/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1
SMILES string
C[Si](C)(C)N([Na])[Si](C)(C)C
InChI key
WRIKHQLVHPKCJU-UHFFFAOYSA-N
form
liquid
concentration
40% in THF
Quality Level
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Application
- Sodium bis(trimethylsilyl)amide, also known as NaHMDS, is a metal dialkylamide reagent that combines both high basicity and nucleophilicity. It is a general reagent used for the enolization of carbonyl compounds.
- It can be used to prepare phosphonium ylides in Wittig reaction.
- NaHMDS solution can also be used as a source of nitrogen in aminomethylation and in the synthesis of primary amines from the corresponding alkyl halides.
Other Notes
signalword
Danger
hcodes
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
supp_hazards
Storage Class
3 - Flammable liquids
wgk
WGK 2
flash_point_f
1.4 °F - closed cup
flash_point_c
-17 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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