808008
OsHCl(CO)[κ3-PyCH2NHC2H4NHPtBu2]
95%, powder or crystals
Synonym(s):
Gusev osmium hydrogenation catalyst
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About This Item
Empirical Formula (Hill Notation):
C18H33ClN3OOsP
CAS Number:
Molecular Weight:
564.13
MDL number:
NACRES:
NA.22
UNSPSC Code:
12352300
Assay:
95%
Form:
powder or crystals
Related Categories
Application
OsHCl(CO)[κ3-PyCH2NHC2H4NHPtBu2] is a robust and highly efficient precatalyst for coupling amines with methanol and ethanol to afford formamides and acetamides. It possesses excellent carbonyl selectivity with an unique activity for acceptorless dehydrogenative coupling of alcohols to esters and amides.
hcodes
signalword
Warning
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Chemoselective hydrogenation of carbonyl compounds and acceptorless dehydrogenative coupling of alcohols.
Spasyuk D, et al.
Journal of the American Chemical Society, 137(11), 3743-3746 (2015)
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