809330
Fe/ppm Pd for nitro group reductions
solid
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About This Item
Product Name
Fe/ppm Pd for nitro group reductions,
form
solid
Quality Segment
composition
FeCl2 (372870), 23.3-27.4 wt. % , MgCl2 (M8266), 15.3-18.8 wt. % , Pd (203939), <0.3 wt. % , THF (186562), 53.5-61.6 wt. %
reaction suitability
core: iron, reagent type: catalyst
storage temp.
2-8°C
SMILES string
[Fe](Cl)(Cl)Cl
InChI key
RBTARNINKXHZNM-UHFFFAOYSA-K
Application
When these nanoparticles (NPs) are used along with PEG-containing designer surfactants such as TPGS-750-M, a facile reduction of nitro compounds can be effected in water at room temperature. The transformation is highly chemoselective and tolerates a large variety of functional groups.
Other Notes
Watch Professor Lipshutz talk about Fe/ppm Pd in this webinar:
From milligrams to kilograms: synthetic chemistry following nature′s lead
From milligrams to kilograms: synthetic chemistry following nature′s lead
Disclaimer
Handle under nitrogen and store under argon in refrigerator.
Signal Word
Danger
Storage Class
3 - Flammable liquids
Flash Point (°F)
1.4 °F
Flash Point (°C)
-17 °C
Hazard Codes
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - STOT SE 3
Target Organs
Central nervous system, Respiratory system
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