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Merck
CN

809330

Fe/ppm Pd for nitro group reductions

solid

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About This Item

UNSPSC Code:
12161600
NACRES:
NA.22
MDL number:
MFCD00011005

Key Documents

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Product Name

Fe/ppm Pd for nitro group reductions,

SMILES string

[Fe](Cl)(Cl)Cl

InChI key

RBTARNINKXHZNM-UHFFFAOYSA-K

form

solid

composition

FeCl2 (372870), 23.3-27.4 wt. % , MgCl2 (M8266), 15.3-18.8 wt. % , Pd (203939), <0.3 wt. % , THF (186562), 53.5-61.6 wt. %

reaction suitability

core: iron, reagent type: catalyst

storage temp.

2-8°C

Quality Level

100

Related Categories

Application

When these nanoparticles (NPs) are used along with PEG-containing designer surfactants such as TPGS-750-M, a facile reduction of nitro compounds can be effected in water at room temperature. The transformation is highly chemoselective and tolerates a large variety of functional groups.

Other Notes

Safe and Selective Nitro Group Reductions Catalyzed by Sustainable and Recyclable Fe/ppm Pd Nanoparticles in Water at Room Temperature
Watch Professor Lipshutz talk about Fe/ppm Pd in this webinar:
From milligrams to kilograms: synthetic chemistry following nature′s lead

Disclaimer

Handle under nitrogen and store under argon in refrigerator.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - STOT SE 3

target_organs

Respiratory system

supp_hazards

EUH018,EUH019

Storage Class

3 - Flammable liquids

wgk

WGK 2

flash_point_f

1.4 °F

flash_point_c

-17 °C

Regulatory Information

危险化学品
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When Does Organic Chemistry Follow Nature?s Lead and ?Make the Switch?.
Lipshutz B H
The Journal of Organic Chemistry, 82(6), 2806-2816 (2017)
New surfactants for chemistry in water.
Krause N
Current opinion in green and sustainable chemistry., 7, 18-22 (2017)
Switching from organic solvents to water at an industrial scale.
Parmentier M, et al.
Current opinion in green and sustainable chemistry., 7, 13-17 (2017)

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Designer surfactants enable diverse transformations like Suzuki-Miyaura, Olefin Metathesis, and 1,4-Addition to Enones in water by Prof. Bruce Lipshutz.

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