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87560

Sigma-Aldrich

Titanium(IV) isopropoxide

≥97.0%

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Synonym(s):
TTIP, Tetraisopropyl orthotitanate
Linear Formula:
Ti[OCH(CH3)2]4
CAS Number:
546-68-9
Molecular Weight:
284.22
Beilstein:
3679474
EC Number:
208-909-6
MDL number:
MFCD00008871
PubChem Substance ID:
57653253
NACRES:
NA.22

Quality Level

200

Assay

≥97.0%

form

liquid

reaction suitability

core: titanium
reagent type: Lewis acid
reagent type: catalyst

refractive index

n20/D 1.464 (lit.)

bp

232 °C (lit.)

mp

14-17 °C (lit.)

density

0.96 g/mL at 20 °C (lit.)

SMILES string

CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C

InChI

1S/4C3H7O.Ti/c4*1-3(2)4;/h4*3H,1-2H3;/q4*-1;+4

InChI key

VXUYXOFXAQZZMF-UHFFFAOYSA-N

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General description

Titanium(IV) isopropoxide is a Lewis acid catalyst used in organic reactions like Sharpless epoxidation.

Application

Novel metal oxide/phosphonate hybrids were formed from titanium(IV) isopropoxide in a two-step sol-gel process. Starting material for barium-strontium-titanate thin films. Used to make porous titanosilicates, potential ion-exchange materials for cleanup of radioactive wastes. Applied in the formation of a heterosupermolecule consisting of a TiO2 nanocrystallite-viologen electron acceptor complex whose light-induced electron transfer has been demonstrated.

Caution

may discolor on storage

Other Notes

Additive used in the Sharpless asymmetric epoxidation of allylic alcohols; Catalyst used for transesterifications with various alcohols under neutral conditions

Pictograms

FlameExclamation mark
GHS02,GHS07

Signal Word

Warning

Hazard Statements

H226 - H319 - H336

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - STOT SE 3

Target Organs

Central nervous system

Storage Class Code

3 - Flammable liquids

WGK

WGK 1

Flash Point(F)

105.8 °F - Pensky-Martens closed cup

Flash Point(C)

41 °C - Pensky-Martens closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

危险化学品

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R. Imwinkelried et al.
Organic Syntheses, 65, 230-230 (1987)
Catalyst design for alkene epoxidation by molecular analogues of heterogeneous titanium-silicalite catalysts
Sole DA, et al.
ACS Catalysis, 10, 4737-4750 (2020)
Alexander V Agafonov et al.
Polymers, 12(9) (2020-09-24)
Electrorheological elastomers based on polydimethylsiloxane filled with hydrated titanium dioxide with a particle size of 100-200 nm were obtained by polymerization of the elastomeric matrix, either in the presence, or in the absence, of an external electric field. The viscoelastic
Henrique Antonio Mendonça Faria et al.
Materials science & engineering. C, Materials for biological applications, 56, 260-268 (2015-08-08)
The structural and electronic properties of titanium oxide nanotubes (TiO2) have attracted considerable attention for the development of therapeutic devices and imaging probes for nanomedicine. However, the fluorescence response of TiO2 has typically been within ultraviolet spectrum. In this study
Yann Sarazin et al.
Dalton transactions (Cambridge, England : 2003), (2)(2), 340-350 (2005-12-21)
The reactions of the bulky amino-bis(phenol) ligand Me(2)NCH(2)CH(2)N[CH(2)-3,5-Bu(t)(2)-C(6)H(2)OH-2](2)(1-H(2)) with Zn[N(SiMe(3))(2)](2)(4), [Mg[N(SiMe(3))(2)](2)](2)(5) and Ca[N(SiMe(3))(2)](2)(THF)(2)(6) yield the complexes 1-Zn, 1-Mg and 1-Ca in good yields. The X-ray structure of 1-Ca showed the complex to be dimeric, with calcium in a distorted octahedral
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