900454
DPPF Pd G4
95%, powder
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About This Item
Empirical Formula (Hill Notation):
C48H43FeNO3P2PdS
CAS Number:
Molecular Weight:
938.14
UNSPSC Code:
12161600
NACRES:
NA.22
MDL number:
Product Name
DPPF Pd G4, 95%
Quality Segment
product line
Buchwald precatalyst Generation 4
assay
95%
form
powder
feature
generation 4
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplings
mp
201 °C
functional group
phosphine
storage temp.
−20°C
SMILES string
CNC1=C(C2=C([Pd]OS(=O)(C)=O)C=CC=C2)C=CC=C1.[C]3(P(C4=CC=CC=C4)C5=CC=CC=C5)[C][C][C][C]3.[C]6(P(C7=CC=CC=C7)C8=CC=CC=C8)[C][C][C][C]6.[Fe]
Application
DPPF Pd G4 is a fourth generation (G4) Buchwald precatalyst that is similar to the third generation (G3) precatalysts except that the amino group on the biphenyl backbone is methylated. This modification helps to prevent the limitations found when using the third generation precatalysts. It is air, moisture, and thermally-stable and shows good solubility in common organic solvents.
Storage Class
11 - Combustible Solids
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
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